First molecular and electronic structure determination of the dicationic salt of 1,11-(methanoselenomethano)-5H,7H-dibenzo[b,g] [1.5]diselenocin by X-ray crystallographic analysis and ab initio calculation
作者： Tsukasa Nakahodo , Ohgi Takahashi , Ernst Horn , Naomichi Furukawa
DOI: 10.1039/A704431C
关键词:
摘要: The X-ray crystallographic analysis of the dication salt of 1,11-(methanoselenomethano)-5H,7H-dibenzo[b,g] [1,5]- diselenocin shows that has a selenium atom in a trigonal-bipyramidal bonding environment; an ab initio calculation carried out for revealed positive charge is exclusively by three atoms.
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