Reactivities, Conformational Properties, and Molecular Structures of σ-Bonded Cyclic Selenurane Dications

作者: Tsukasa Nakahodo , Ohgi Takahashi , Ernst Horn , Naomichi Furukawa

DOI: 10.1080/10426509808545997

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摘要: Abstruct: The synthesis of σ-selenurane dication salts via transannular interactions and the reactivities these are described. X-ray crystallographic analyses show that dications have selenium atoms in a trigonal-bipyramidal bonding environment. Ab initio calculations carried out for revealed exclusively carry positive charge. interesting conformational properties also

参考文章(7)
Hisashi Fujihara, Hisatomo Mima, Tomoki Erata, Naomichi Furukawa, A new tetracoordinated cyclic diazaselenurane with amino and ammonio groups as two unsymmetrical apical ligands and its bisammonioselenurane Journal of the American Chemical Society. ,vol. 115, pp. 9826- 9827 ,(1993) , 10.1021/JA00074A070