Asymmetric dihydroxylation of linalool, nerolidol and citronellyl acetate. Enantioselective synthesis of (3S, 6S)-tetrahydro-2,2,6-trimethyl-6-vinyl-2H-pyran-3-ol
作者： Giovanni Vidari , Andrea Giori , Antonella Dapiaggi , Gianluigi Lanfranchi
DOI: 10.1016/S0040-4039(00)91832-X
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摘要: Abstract The asymmetric Sharpless' dihydroxylation of linalool, citronellyl acetate and nerolidol was investigated. High diastereo-, enantio- positional selectivity observed for the first two terpenes. A highly diastereo- enantioselective synthesis (3S,6S)-tetrahydro- 2,2,6-trimethyl- 6-vinyl-2H -pyran-3-ol is described.
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