Specific heat of Fe3O4−xFx in the neighbourhood of the verwey temperature (with x=0, 0.1 and 0.25)

作者: M.O. Rigo , J. Kleinclauss , A.J. Pointon

DOI: 10.1016/0038-1098(78)90661-0

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摘要: Abstract The partial substitution of oxygen by fluorine, in magnetite, has allowed us to increase the concentration Fe 2+ ions and modify ratio ( 3+ ) oct. without introducing a foreign cation. Studies specific heat X-ray diffraction at temperatures near that Verwey temperature show crystallographic transformation is linked existence octahedral ions.

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