Distortions in trihapto-allyls induced by electronic asymmetry: A comparison of the structures of (η5-C5H5)Mo(CO)2(η3-C3H5) and (η5-C5H5)Mo(NO(I)(η3-C3H5)
作者： J.W. Faller , D.F. Chodosh , D. Katahira
DOI: 10.1016/S0022-328X(00)81791-X
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摘要: Abstract The electronic asymmetry induced by replacing two carbonyls a nitrosyl and iodide ligand causes severe distortion in the allyl moiety. group complex is bound sigma-pi mode rather than symmetrical found dicarbonyl. This change ground state structure alters exo—endo conformer interconversion mechanism from rotation of dicarbonyl to iodide.
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