The effect of binary antioxidant proportions on antioxidant synergy and oxidation stability of Jatropha and Karanja biodiesels.
作者： Devendra S Rawat , Girdhar Joshi , Bhawna Y Lamba , Avanish K Tiwari , Pankaj Kumar
DOI: 10.1016/J.ENERGY.2015.03.024
关键词:
摘要: Abstract Oxidation has been measured a major problem for biodiesel commercialization. Auto-oxidation takes place when exposed to air, heat, light and metallic contaminants which affects adversely the fuel characteristics of biodiesel. Addition synthetic antioxidants generally improves oxidation stability biodiesel; however use large concentration additives makes process uneconomical. This study investigates effectiveness individual as well binary improve Jatropha Karanja biodiesels. Antioxidant synergy was investigated using 500, 600 700 ppm antioxidant combinations namly Pyrogallol:Propyl gallate (PY:PrG), Pyrogallol:tert-butyl hydroquinone (PY:TBHQ) Pyrogallol:Butylated hydroxyanisole (PY:BHA) at weight ratios 9:1, 3:1, 2:1, 1:1, 1:2, 1:3 1:9, respectively. It observed that higher blends mixture produced negative synergy, best showed by systems PY:PrG, PY:TBHQ, are mixed ratios; whereas PY:BHA resulted in complete antagonism. However, system on found order 1:3/3:1 > 1:2/2:1 > 1:1 > 1:9/9:1. The efficacy evaluated pressurized PetroOXY method. Further dependency fatty acid composition also observed.
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sci-hub.se 参考文章(32)
N Kapilan, TP Ashok Babu, RP Reddy, Technical aspects of biodiesel and its oxidation stability. International Journal of ChemTech Research. ,vol. 1, pp. 278- 282 ,(2009)
E Niki, T Saito, A Kawakami, Y Kamiya, Inhibition of oxidation of methyl linoleate in solution by vitamin E and vitamin C. Journal of Biological Chemistry. ,vol. 259, pp. 4177- 4182 ,(1984) , 10.1016/S0021-9258(17)43026-2
Handbook of Antioxidants CRC Press. ,(2001) , 10.1201/9780203904046
Walter Oscar Lundberg, AUTOXIDATION AND ANTIOXIDANTS ,(1961)
Brajendra K. Sharma, Joseph M. Perez, Sevim Z. Erhan, Soybean Oil-Based Lubricants: A Search for Synergistic Antioxidants† Energy & Fuels. ,vol. 21, pp. 2408- 2414 ,(2007) , 10.1021/EF0605854
Mohamed Bouaziz, Ines Fki, Hedya Jemai, Mohamed Ayadi, Sami Sayadi, Effect of storage on refined and husk olive oils composition: Stabilization by addition of natural antioxidants from Chemlali olive leaves Food Chemistry. ,vol. 108, pp. 253- 262 ,(2008) , 10.1016/J.FOODCHEM.2007.10.074
Eleonora Miquel Becker, Georgia Ntouma, Leif H. Skibsted, Synergism and antagonism between quercetin and other chain-breaking antioxidants in lipid systems of increasing structural organisation Food Chemistry. ,vol. 103, pp. 1288- 1296 ,(2007) , 10.1016/J.FOODCHEM.2006.10.034
Haiying Tang, Rhet C. De Guzman, K. Y. Simon Ng, Steven O. Salley, Effect of Antioxidants on the Storage Stability of Soybean-Oil-Based Biodiesel Energy & Fuels. ,vol. 24, pp. 2028- 2033 ,(2010) , 10.1021/EF9012032
R.L. McCormick, M. Ratcliff, L. Moens, R. Lawrence, Several factors affecting the stability of biodiesel in standard accelerated tests Fuel Processing Technology. ,vol. 88, pp. 651- 657 ,(2007) , 10.1016/J.FUPROC.2007.01.006