Effect of Antioxidants on the Storage Stability of Soybean-Oil-Based Biodiesel

作者: Haiying Tang , Rhet C. De Guzman , K. Y. Simon Ng , Steven O. Salley

DOI: 10.1021/EF9012032

关键词:

摘要: Biodiesel is composed of the monoalkyl esters produced from a variety animal fats or vegetable oils, which can be used in blends with conventional petroleum diesel existing engines. While having many desirable properties, poor oxidative and storage stabilities are source considerable concern. This paper presents results studies on effectiveness various individual binary antioxidants [(α-tocopherol (α-T), butylated hydroxyanisole (BHA), butyl-4-methylphenol (BHT), t-butylhydroquinone (TBHQ), 2,5-ditert-butyl-hydroquinone (DTBHQ), ionol BF200 (IB), propylgallate (PG), pyrogallol (PY)] to improve stability soybean oil (SBO)- distilled SBO-based biodiesel. Results indicate that induction period (IP) untreated biodiesel significantly decreased increasing time, while IP values adding TBHQ remained constant for up 30 months. Moreover, antioxidant formulations THBQ/BHA maintain...

参考文章(17)
Takashi Hoshino, Yusaku Iwata, Hiroshi Koseki, Oxidation stability and risk evaluation of biodiesel Thermal Science. ,vol. 11, pp. 87- 100 ,(2007) , 10.2298/TSCI0702087H
Oliver Falk, Roland Meyer-Pittroff, The effect of fatty acid composition on biodiesel oxidative stability EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY. ,vol. 106, pp. 837- 843 ,(2004) , 10.1002/EJLT.200400978
Cherng-Yuan Lin, Chu-Chiang Chiu, EFFECTS OF OXIDATION DURING LONG-TERM STORAGE ON THE FUEL PROPERTIES OF PALM OIL-BASED BIODIESEL Energy & Fuels. ,vol. 23, pp. 3285- 3289 ,(2009) , 10.1021/EF900105T
Chao Liang, Koen Schwarzer, Comparison of Four Accelerated Stability Methods for Lard and Tallow With and Without Antioxidants Journal of the American Oil Chemists' Society. ,vol. 75, pp. 1441- 1443 ,(1998) , 10.1007/S11746-998-0196-3
Bryan R. Moser, Biodiesel production, properties, and feedstocks In Vitro Cellular & Developmental Biology – Plant. ,vol. 45, pp. 229- 266 ,(2009) , 10.1007/S11627-009-9204-Z
Haiying Tang, Anfeng Wang, Steven O. Salley, K. Y. Simon Ng, Effect of natural and synthetic antioxidants on the oxidative stability of biodiesel Journal of the American Oil Chemists' Society. ,vol. 85, pp. 373- 382 ,(2009) , 10.1007/S11746-008-1208-Z
Y LIANG, C MAY, C FOON, M NGAN, C HOCK, Y BASIRON, The effect of natural and synthetic antioxidants on the oxidative stability of palm diesel Fuel. ,vol. 85, pp. 867- 870 ,(2006) , 10.1016/J.FUEL.2005.09.003
Rhet de Guzman, Haiying Tang, Steven Salley, K. Y. Simon Ng, Synergistic Effects of Antioxidants on the Oxidative Stability of Soybean Oil- and Poultry Fat-Based Biodiesel Journal of the American Oil Chemists' Society. ,vol. 86, pp. 459- 467 ,(2009) , 10.1007/S11746-009-1373-8