Determination of the electric dipole moment of the HSO radical in its and electronic states
作者： Christopher R. Webster , Philip J. Brucat , Richard N. Zare
DOI: 10.1016/0022-2852(82)90093-5
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摘要: Abstract Stark shifts were measured for the zero-field-allowed 000-110, 110-000 and zero-field-forbidden 000-111, 111-000 lines of HSO A 2 A′(003)- X A″(000) transition. single-mode dye laser is used to record Doppler-limited fluorescence excitation spectrum as a function applied electric field (0–11 kV/cm) polarizations parallel perpendicular direction. The dipole moment along axis this near-prolate asymmetric top determined be μ″a = 2.20 ± 0.08 D μ′a 1.05 D, in close agreement with recent ab initio calculations.
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