Dipole moments of H2CS in the Ã1A2 (v = 0) and ã3A2 (v3 = 1) states by MODR spectroscopy

作者: Tetsuo Suzuki , Shuji Saito , Eizi Hirota

DOI: 10.1016/0022-2852(85)90067-0

关键词: Moment (physics)PhysicsAtomic physicsNuclear magnetic resonanceLaserDipoleMeasure (mathematics)SpectroscopyExcited stateStark effectResonance (particle physics)

摘要: Abstract The microwave-optical double resonance (MODR) technique was used to measure the Stark effects of H2CS in A 1 2 (v = 0) and a 3 1) states, from which dipole moment has been calculated be 0.850(2)D 0.548(9)D for two respectively, where numbers parentheses denote one standard error apply last digits. effect measurement using MODR compared with that Doppler-limited laser excited fluorescence.

参考文章(22)
Christopher R. Webster, Philip J. Brucat, Richard N. Zare, Determination of the electric dipole moment of the HSO radical in its and electronic states Journal of Molecular Spectroscopy. ,vol. 92, pp. 184- 202 ,(1982) , 10.1016/0022-2852(82)90093-5
Stuart J. Silvers, Thomas H. Bergeman, William Klemperer, Level Crossing and Double Resonance on the A 1π State of CS The Journal of Chemical Physics. ,vol. 52, pp. 4385- 4399 ,(1970) , 10.1063/1.1673661
P.J. Bruna, S.D. Peyerimhoff, R.J. Buenker, P. Rosmus, Non-empirical SCF and Cl Study of the ground and excited states of thioformaldehyde principles and practice of constraint programming. ,vol. 3, pp. 35- 53 ,(1974) , 10.1016/0301-0104(74)80074-1
Ethan A. Scarl, F. W. Dalby, High-Field Stark Effects on the Near Ultraviolet Spectrum of the Hydroxyl Radical Canadian Journal of Physics. ,vol. 49, pp. 2825- 2832 ,(1971) , 10.1139/P71-340
J.M. Brown, S.W. Chalkley, F.D. Wayne, Determination of the dipole moment of the amino radical by optical Stark spectroscopy with a tunable dye laser Molecular Physics. ,vol. 38, pp. 1521- 1537 ,(1979) , 10.1080/00268977900102621
P.G. Burton, S.D. Peyerimhoff, R.J. Buenker, Theoretical studies of the electronic spectrum of thioformaldehyde Chemical Physics. ,vol. 73, pp. 83- 98 ,(1982) , 10.1016/0301-0104(82)85151-3