Level Crossing and Double Resonance on the A 1π State of CS
作者： Stuart J. Silvers , Thomas H. Bergeman , William Klemperer
DOI: 10.1063/1.1673661
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摘要: Using the coincident atomic spectral line MnII 2576.1 to pump R(7) transition of 0–0 band, level crossing and double resonance are observed in 1Π state carbon monosulfide. From Hanle effect a lifetime value 2.0 ± 0.4 × 10−7 sec is obtained. The analogous Stark Stark–Zeeman recrossing give estimates dipole moment μ lambda doubling δ. With an rf search aided by these estimates, optical‐rf provides more accurate values: μ8 = 0.68 ± 0.01 D; δ8 = 1099.4 ± 0.3 MHz for J = 8 level. Considering nearby perturbing states, it estimated that μΠ = μ8 ± 0.08 D. A derivation signal intensity experiment used obtain power requirements criteria selecting optimum polarization.
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