Enantioselective behaviors of cis-epoxiconazole in vegetables-soil-earthworms system by liquid chromatography-quadrupole-time-of-flight mass spectrometry
作者： Peipei Qi , Shanshan Di , Tao Cang , Xuewei Yang , Xiangyun Wang
DOI: 10.1016/J.SCITOTENV.2019.136039
关键词:
摘要: Abstract Cis-epoxiconazole is a widely used triazole fungicide for control and prevention of series fungal diseases in fruits, vegetables, teas grains. The present work aimed at exploring enantioselective behavior cis-epoxiconazole the vegetable-soil-earthworm system. Firstly, absolute configuration enantiomers was ascertained. Secondly, degradation cabbage, pakchoi pepper were performed under field trials, which has not been previously reported. Enantioselective occurred cabbage samples. 2R, 3S-(+)-cis-epoxiconazole degraded faster than 2S, 3R-(−)-cis-epoxiconazole while reversed results obtained pepper. No observed pakchoi. Finally, soil principal reservoir environmental pesticides, so behaviors organism (earthworm, Eisenia fetida) evaluated. Similar bioaccumulation curves earthworms exposure levels 1 10 mg/kg. Accumulation factors (AFs) indicated had weak potential to contaminated soil, no obvious enantioselectivity observed. different enantioselectivities vegetables illuminated that preferentially enriched enantiomer might impose higher risk on human health other one, high required further assessment. These may reduce uncertainty
sci-hub.se 参考文章(30)
Philipp Egeler, Michael Meller, Joerg Roembke, Peter Spoerlein, Bruno Streit, Roland Nagel, Tubifex tubifex as a link in food chain transfer of hexachlorobenzene from contaminated sediment to fish Hydrobiologia. ,vol. 463, pp. 171- 184 ,(2001) , 10.1007/978-94-010-0597-5_18
Dezhen Wang, Jing Qiu, Wentao Zhu, Ping Zhang, Nian Deng, Xinru Wang, Yao Wang, Zhiqiang Zhou, Evaluating the enantioselective distribution, degradation and excretion of epoxiconazole in mice following a single oral gavage. Xenobiotica. ,vol. 45, pp. 1009- 1015 ,(2015) , 10.3109/00498254.2015.1033778
Vera LSS de Castro, Aline H Maia, None, Prenatal epoxiconazole exposure effects on rat postnatal development. Birth Defects Research Part B-developmental and Reproductive Toxicology. ,vol. 95, pp. 123- 129 ,(2012) , 10.1002/BDRB.20345
Xiaotian Lv, Chen Liu, Yaobin Li, Yongxin Gao, Huili Wang, Jianzhong Li, Baoyuan Guo, Stereoselectivity in bioaccumulation and excretion of epoxiconazole by mealworm beetle (Tenebrio molitor) larvae. Ecotoxicology and Environmental Safety. ,vol. 107, pp. 71- 76 ,(2014) , 10.1016/J.ECOENV.2014.02.013
Qing Zhang, Xiu-de Hua, Hai-yan Shi, Ji-song Liu, Ming-ming Tian, Ming-hua Wang, Enantioselective bioactivity, acute toxicity and dissipation in vegetables of the chiral triazole fungicide flutriafol Journal of Hazardous Materials. ,vol. 284, pp. 65- 72 ,(2015) , 10.1016/J.JHAZMAT.2014.10.033
J. R. Bertelsen, E. De Neergaard, V. Smedegaard-Petersen, Fungicidal effects of azoxystrobin and epoxiconazole on phyllosphere fungi, senescence and yield of winter wheat Plant Pathology. ,vol. 50, pp. 190- 205 ,(2001) , 10.1046/J.1365-3059.2001.00545.X
Brad J. Konwick, Arthur W. Garrison, Jimmy K. Avants, Aaron T. Fisk, Bioaccumulation and biotransformation of chiral triazole fungicides in rainbow trout (Oncorhynchus mykiss) Aquatic Toxicology. ,vol. 80, pp. 372- 381 ,(2006) , 10.1016/J.AQUATOX.2006.10.003
Jin-Hui Chen, Hui-Li Wang, Bao-Yuan Guo, Jian-Zhong Li, LC-MS/MS method for simultaneous determination of myclobutanil, hexaconazole, diniconazole, epoxiconazole and tetraconazole enantiomers in soil and earthworms International Journal of Environmental Analytical Chemistry. ,vol. 94, pp. 791- 800 ,(2014) , 10.1080/03067319.2013.853763
Jing Qiu, Li Li, Wei Li, Zhiqiang Zhou, Fengmao Liu, Lihong Qiu, Hongwu Liang, Stereoselective dissipation of epoxiconazole in grape (Vitis vinifera cv. Kyoho) and soil under field conditions. Chemosphere. ,vol. 87, pp. 982- 987 ,(2012) , 10.1016/J.CHEMOSPHERE.2012.02.038
C. R. Worthing, The pesticide manual, a world compendium. British Crop Protection Council. ,(1979)