Behavior of OsH2Cl2(PiPr3)2 in Acetonitrile: The Importance of the Small Details
作者： Miguel A. Esteruelas , Sara Fuertes , Montserrat Oliván , Enrique Oñate
DOI: 10.1021/OM801057Z
关键词:
摘要: Financial support from the MICINN of Spain (Project No. CTQ2008-00810 and Consolider Ingenio 2010 CSD2007-00006) Diputacion General de Aragon (E35) is acknowledged.
acs.org
sci-hub.se 参考文章(28)
Miguel A. Esteruelas, Fernando J. Lahoz, Luis A. Oro, Enrique Onate, Natividad Ruiz, Syntheses, spectroscopic characterizations, and X-ray structures of new Os({eta}{sup 2}-H{sub 2}) compounds containing azole ligands Inorganic Chemistry. ,vol. 33, pp. 787- 792 ,(1994) , 10.1021/IC00082A027
Miguel A. Esteruelas, Francisco J. Fernández-Alvarez, Enrique Oñate, Osmium and Ruthenium Complexes Containing an N-Heterocyclic Carbene Ligand Derived from Benzo[h]quinoline Organometallics. ,vol. 26, pp. 5239- 5245 ,(2007) , 10.1021/OM700639A
Kjell-Tore Smith, Mats Tilset, Roger Kuhlman, Kenneth G. Caulton, Reactions of (PiPr3)2OsH6 Involving Addition of Protons and Removal of Electrons. Characterization of (PiPr3)2Os(NCMe)xHyz+ (x = 0, 2, 3; y = 1, 2, 3, 4, 7; z = 1, 2), Including Dicationic .eta.2-H2 Complexes Journal of the American Chemical Society. ,vol. 117, pp. 9473- 9480 ,(1995) , 10.1021/JA00142A013
Peter J. Desrosiers, Lisheng Cai, Zerong Lin, Rosalie Richards, Jack Halpern, Assessment of the T1 criterion for distinguishing between classical and nonclassical transition-metal hydrides : hydride relaxation rates in tris(triarylphosphine)osmium tetrahydrides and related polyhydrides Journal of the American Chemical Society. ,vol. 113, pp. 4173- 4184 ,(1991) , 10.1021/JA00011A019
Roger Kuhlman, William E. Streib, Kenneth G. Caulton, Protonation of Chloride in Os(H)2Cl2(PiPr3)2: Synthesis of [(PiPr3)2H2Os(.mu.-Cl)3OsH2(PiPr3)2]CF3SO3 Inorganic Chemistry. ,vol. 34, pp. 1788- 1792 ,(1995) , 10.1021/IC00111A028
Miguel A. Esteruelas, Luis A. Oro, Dihydrogen Complexes as Homogeneous Reduction Catalysts Chemical Reviews. ,vol. 98, pp. 577- 588 ,(1998) , 10.1021/CR970322U
Andrew J. Edwards, Miguel A. Esteruelas, Fernando J. Lahoz, Ana M. López, Enrique Oñate, Luis A. Oro, José I. Tolosa, REACTIVITY OF OSH2CL2(PIPR3)2 TOWARD DIOLEFINS : NEW REACTIONS INVOLVING C-H AND C-C ACTIVATION AND C-C AND C-P BOND FORMATION PROCESSES Organometallics. ,vol. 16, pp. 1316- 1325 ,(1997) , 10.1021/OM960969P
Melvyn Rowen Churchill, Susan A. Bezman, X-ray crystallographic studies on fluxional pentacoordinate transition metal complexes. III. (Cycloocta-1,5-diene)[bis(1,3-diphenylphosphino)propane]methyliridium(I) Inorganic Chemistry. ,vol. 12, pp. 531- 536 ,(1973) , 10.1021/IC50121A006
Dmitry G. Gusev, Roger Kuhlman, Joe R. Rambo, Heinz Berke, Odile Eisenstein, Kenneth G. Caulton, Structural and Dynamic Properties of OsH2X2L2 (X = Cl, Br, I; L = PiPr3) Complexes: Interconversion between Remarkable Non-Octahedral Isomers Journal of the American Chemical Society. ,vol. 117, pp. 281- 292 ,(1995) , 10.1021/JA00106A031
Kelly A. Earl, Guochen Jia, Patricia A. Maltby, Robert H. Morris, .eta.2-Dihydrogen on the brink of homolytic cleavage: trans-[Os(H.cntdot..cntdot..cntdot.H)H(PEt2CH2CH2PEt2)2]+ has spectroscopic and chemical properties between those of the isoelectronic complexes trans-[OsH(PPh2CH2CH2PPh2)2(.eta.2-H2)]+ and ReH3(PPh2CH2CH2PPh2)2 Journal of the American Chemical Society. ,vol. 113, pp. 3027- 3039 ,(1991) , 10.1021/JA00008A035