Microporous network‐assisted formation of copper‐in‐polymer gradient composite film
作者： Bo Yang , Jianguo Tang , Peihua Yang , Yao Wang , Jixian Liu
DOI: 10.1002/APP.36931
关键词:
摘要: In this article, a copper-in-polymer-gradient composite film (CPGCF) was synthesized by electrochemical strategy via reducing solvent-swollen cathode (SCF). The latex nanoparticles of ternary copolymer including styrene, butyl acrylate, and acrylic acid structural units play the key role to form well-graded copper distribution in matrix through porous morphological structure developed nanoparticle semimelt joining. along cross-section CPGCF includes three layers: (1) dense layer whose most outside originally attached reactor, (2) shrublike that grew from layer, (3) clear which there is no obvious reduced phase contacted with liquid electrolyte medium reactor. As experimental aspects, influences emulsion polymerization conditions copolymer, predrying time temperature SCF, dc voltage reduction on were investigated. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci,
sci-hub.se 参考文章(24)
A VANTENT, K TENIJENHUIS, The film formation of polymer particles in drying thin films of aqueous acrylic latices. II. Coalescence, studied with transmission spectrophotometry Journal of Colloid and Interface Science. ,vol. 232, pp. 350- 363 ,(2000) , 10.1016/S0021-9797(00)97189-3
Karl Doblhofer, Mikhail Vorotyntsev, The Membrane Properties of Electroactive Polymer Films Springer US. pp. 375- 442 ,(1994) , 10.1007/978-1-4757-5070-6_3
Helen M. Woods, Marta M. C. G. Silva, C�cile Nouvel, Kevin M. Shakesheff, Steven M. Howdle, Materials processing in supercritical carbon dioxide: surfactants, polymers and biomaterials Journal of Materials Chemistry. ,vol. 14, pp. 1663- 1678 ,(2004) , 10.1039/B315262F
Navin Chand, U.K. Dwivedi, M.K. Sharma, Development and tribological behaviour of UHMWPE filled epoxy gradient composites Wear. ,vol. 262, pp. 184- 190 ,(2007) , 10.1016/J.WEAR.2006.04.012
Qiang Wang, Tie Liu, Ao Gao, Chao Zhang, Chunjiang Wang, Jicheng He, A novel method for in situ formation of bulk layered composites with compositional gradients by magnetic field gradient Scripta Materialia. ,vol. 56, pp. 1087- 1090 ,(2007) , 10.1016/J.SCRIPTAMAT.2007.02.026
O. D. Velev, T. A. Jede, R. F. Lobo, A. M. Lenhoff, Microstructured Porous Silica Obtained via Colloidal Crystal Templates Chemistry of Materials. ,vol. 10, pp. 3597- 3602 ,(1998) , 10.1021/CM980444I
P.A. Steward, J. Hearn, M.C. Wilkinson, An overview of polymer latex film formation and properties. Advances in Colloid and Interface Science. ,vol. 86, pp. 195- 267 ,(2000) , 10.1016/S0001-8686(99)00037-8
Jianguo Tang, Qiang Chen, Haiyan Liu, Yao Wang, Influences of co‐monomers and electrolyte acidity on morphological structure of copper‐in‐copolymer gradient film Journal of Applied Polymer Science. ,vol. 92, pp. 373- 380 ,(2004) , 10.1002/APP.20045
Bor-J. Niu, Marek W. Urban, Recent advances in stratification and film formation of latex films; attenuated total reflection and step‐scan photoacoustic FTIR spectroscopic studies Journal of Applied Polymer Science. ,vol. 70, pp. 1321- 1348 ,(1998) , 10.1002/(SICI)1097-4628(19981114)70:7<1321::AID-APP9>3.0.CO;2-O
Hong-Bo Sun, Junfeng Song, Ying Xu, Shigeki Matsuo, Hiroaki Misawa, Guotong Du, Shiyong Liu, Growth and property characterizations of photonic crystal structures consisting of colloidal microparticles Journal of The Optical Society of America B-optical Physics. ,vol. 17, pp. 476- 480 ,(2000) , 10.1364/JOSAB.17.000476