Kinetic Modeling of Hydrocarbon Processing and the Effect of Catalyst Deactivation by Coke Formation

摘要: Previously derived fundamental rate equations for coke formation and catalyst deactivation are applied to the modeling of a number commercial processes: steam reforming natural gas, styrene production from ethylbenzene, catalytic cracking heavy oil fractions, methanol‐to‐olefins on SAPO 34, solid acid alkylation Y zeolite. The accounts in great detail chemistry process, including deactivating agent, commonly called coke. It is shown that agent not an inert substance but involved reactions, sometimes same type as those leading main products process.