Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis.

作者: Elham Askarizadeh , Sahar Bani Yaghoob , Davar M. Boghaei , Alexandra M. Z. Slawin , Jason B. Love

DOI: 10.1039/B923189G

关键词:

摘要: By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes tune reactivity this system towards catalytic four-electron reduction dioxygen water.

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