Measurements of stratospheric ClO over Antarctica in 1996-2000 and implications for ClO dimer chemistry
作者： Philip Solomon , Brian Connor , James Barrett , Thomas Mooney , Adrian Lee
DOI: 10.1029/2002GL015232
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摘要: [1] Measurements of ClO over Antarctica during the 1996 to 2000 ozone holes are compared with predictions SLIMCAT model. The model captures all major features measurements, including rapid rise in August, drop mid or late September due arrival warmer, ClOx poor air overhead, and deactivation into reservoir species, HCl ClONO2 air. uses standard JPL rates for photolysis dimer (j) forward reaction forming (kf). predicted mixing ratios columns excellent agreement measurements. A comparison data 5 years leads a value ratio (j/kf) consistent value, namely 1.06 ± 0.30(j/kf)JPL.
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