INVESTIGATION ON LOW-SPIN COBALT(II) COMPLEXES. II. AN ESR STUDY OF THE SCHIFF BASE COMPLEXES OF THE PLANAR cis-[CoN2O2] TYPE
作者： Yuzo Nishida , Sigeo Kida
DOI: 10.1246/CL.1973.57
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摘要: ESR spectra of nine Schiff base complexes the planar cis-[CoN2O2] type were measured in host crystals nickel(II) homologues. The showed rhombic patterns, three eight-lined hyperfine structures due to 59Co being resolved. theoretical discussion on these data led conclusion that ground state an unpaired electron hauses dyz(or dxz) orbital.
csj.jp参考文章(8)
Yuzo Nishida, Sigeo Kida, Magnetic Moments and Electronic Spectra of Low-spin Cobalt(II) Complexes Bulletin of the Chemical Society of Japan. ,vol. 45, pp. 461- 465 ,(1972) , 10.1246/BCSJ.45.461
B. Bosnich, An interpretation of the circular dichroism and electronic spectra of salicylaldimine complexes of square-coplanar diamagnetic nickel(II) Journal of the American Chemical Society. ,vol. 90, pp. 627- 632 ,(1968) , 10.1021/JA01005A012
Hideo Yamatera, On the Absorption Spectra of Hexamminecobalt (III) and Related Complexes. II. Theoretical Study on Shifting and Spilitting of the First and the Second Band Due to Substitution of Ligands Bulletin of the Chemical Society of Japan. ,vol. 31, pp. 95- 108 ,(1958) , 10.1246/BCSJ.31.95
Hiroaki Nishikawa, Shoichiro Yamada, Planar Quadri-co-ordinate Complexes of Cobalt(II) with Schiff Bases Derived from Salicylaldehyde Bulletin of the Chemical Society of Japan. ,vol. 37, pp. 8- 12 ,(1964) , 10.1246/BCSJ.37.8
Yuzo Nishida, Sigeo Kida, A Study of Electronic Spectra of Square Planar Copper(II) and Nickel(II) Complexes by Circular Dichroism Bulletin of the Chemical Society of Japan. ,vol. 43, pp. 3814- 3819 ,(1970) , 10.1246/BCSJ.43.3814
R. Linn Belford, T.S. Piper, Comments on visible spectra of Cu and Ni chelates of tetradentate Schiff's bases Molecular Physics. ,vol. 5, pp. 251- 255 ,(1962) , 10.1080/00268976200100271
L.M. Engelhardt, J.D. Duncan, Michael Green, The ESR of some low spin cobalt(II)-N4 and -N2O2 complexes Inorganic and Nuclear Chemistry Letters. ,vol. 8, pp. 725- 732 ,(1972) , 10.1016/0020-1650(72)80126-0
Louis D. Rollmann, Sunney I. Chan, Quadrupole Effects in Electron Paramagnetic Resonance Spectra of Polycrystalline Copper and Cobalt Complexes The Journal of Chemical Physics. ,vol. 50, pp. 3416- 3431 ,(1969) , 10.1063/1.1671565