Effective Recognition of Different Types of Amino Groups: From Aminobenzenesulfonamides to Amino-(N-alkyl)benzenesulfonamides via Iridium-Catalyzed N-Alkylation with Alcohols
作者： Lei Lu , Juan Ma , Panpan Qu , Feng Li
DOI: 10.1021/ACS.ORGLETT.5B00824
关键词:
摘要: A simple, highly efficient, and general strategy for the direct synthesis of amino-(N-alkyl)benzenesulfonamides has been accomplished via N-alkylation aminobenzenesulfonamides bearing both different types amino groups with alcohols as alkylating agents. Notably, this research exhibited potential recognition in complex molecules alcohols, facilitating progress transition-metal-catalyzed “hydrogen autotransfer (or hydrogen-borrowing) process.”
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