Radiolysis of alkyl substituted tridentate 2,6-bis(1,2,4-triazine-3-yl)pyridines: an experimental study with DFT validation
作者： Qi Pan , Yue Wang , Jian Chen , Long Zhao , Jiuqiang Li
DOI: 10.1039/C8NJ04273J
关键词:
摘要: The radiolysis products of alkyl substituted tridentate 2,6-bis(1,2,4-triazine-3-yl)pyridines (BTPs) were studied by an experimental study with DFT validation. Based on the analysis various spectroscopic methods (Micro-FTIR, 1H NMR, and high-resolution ESI-MS), C–C cleavage, oxidation, hydroxylation, dehydrogenation BTPs are confirmed as main radiation-induced reactions BTPs. possible reaction positions in proposed.
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