Laser-induced dealkylation of calix[4]arene-crown-6 ethers
作者： Christopher K. Jankowski , Celine Hocquelet , Sebastien Arseneau , Christophe Moulin , Laurent Mauclaire
DOI: 10.1016/J.JPHOTOCHEM.2006.04.018
关键词: Organic chemistry 、 Alkylation 、 Chemistry 、 Laser 、 Crown (botany) 、 Medicinal chemistry
摘要: Abstract Selective dealkylation of dialkyl calix[4]arene monocrown-6 and biscrown-6 was achieved using laser irradiation. The resulting phenolic compounds structures, studied by NMR (1H 13C) ESI-MS (Cs+ spiking), probably originated from their partial photo-Claisen rearrangement.
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