Iridium and rhodium complexes with tetrafluorobenzobarrelene diolefins

作者: Miguel A. Esteruelas , Luis A. Oro

DOI: 10.1016/S0010-8545(99)00082-X

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摘要: Abstract Iridium and rhodium complexes with tetrafluorobenzobarrelene (5,6,7,8-tetrafluoro-1,4-dihydro-1,4-ethenonaphthalene) type diolefins are reviewed. The synthesis of these compounds has promoted the development a rich chemistry, including catalysis, neutral cationic, mono- polynuclear containing iridium or rhodium–tetrafluorobenzobarrelene moieties, which show significant differences respect to chemistry usual diolefins.

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