Cationic organometallic complexes with hexaalkylborazines: I. Synthesis and reactivity of cationic hexamethylborazinerhodium complexes with carbonyl, ethylene and diolefins as ligands
作者： M. Scotti , M. Valderrama , R. Ganz , H. Werner
DOI: 10.1016/0022-328X(85)80053-X
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摘要: Abstract The PF 6 salts of the new cationic hexamethylborazinerhodium(I) complexes general formula [Rh(Me 3 B N Me )(LL′)] + (LL′= 1,5-cyclooctadiene, norbornadiene, tetrafluorobenzobarrelene, trimethyltetrafluorobenzobarrelene, L = L′ ethylene, CO) have been prepared from reaction between [RhCl(LL′)] 2 , NMe and AgPF in dichloromethane. These are very labile, undergoing rapid ring ligand exchange solution with σ π-donor ligands. synthesis [Rh(η -naphthalene)(COD)]PF is also described. properties NMR IR spectroscopic characteristics compounds briefly discussed.
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