Enzymatic synthesis of hydrophilic and hydrophobic derivatives of natural phenolic acids in organic media
作者： H. Stamatis , V. Sereti , F.N. Kolisis
DOI: 10.1016/S1381-1177(00)00016-3
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摘要: The enzymatic esterification of natural phenolic antioxidants such as cinnamic acid and benzoic derivatives, with aliphatic alcohols, monosaccharides well alkylglucosides, using various lipases esterases in non-aqueous media, was investigated. Reaction rate yield seems to be linked the structural characteristics substrates (aromatic acids alcohols or sugars) used.
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sci-hub.se 参考文章(15)
Ralf T. Otto, Uwe T. Bornscheuer, Christoph Syldatk, Rolf D. Schmid, Synthesis of aromatic n-alkyl-glucoside esters in a coupled β-glucosidase and lipase reaction Biotechnology Letters. ,vol. 20, pp. 437- 440 ,(1998) , 10.1023/A:1005367215303
B. Guyot, B. Bosquette, M. Pina, J. Graille, Esterification of phenolic acids from green coffee with an immobilized lipase from Candida antarctica in solvent-free medium Biotechnology Letters. ,vol. 19, pp. 529- 532 ,(1997) , 10.1023/A:1018381102466
G.J.H. Buisman, C.T.W. van Helteren, G.F.H. Kramer, J.W. Veldsink, J.T.P Derksen, F.P. Cuperus, Enzymatic esterifications of functionalized phenols for the synthesis of lipophilic antioxidants Biotechnology Letters. ,vol. 20, pp. 131- 136 ,(1998) , 10.1023/A:1005368222340
H. Chimi, J. Cillard, P. Cillard, M. Rahmani, Peroxyl and hydroxyl radical scavenging activity of some natural phenolic antioxidants Journal of the American Oil Chemists' Society. ,vol. 68, pp. 307- 312 ,(1991) , 10.1007/BF02657682
Lei Liu, W. Robert Hudgins, Sonsoles Shack, Mu Quan Yin, Dvorit Samid, Cinnamic acid: a natural product with potential use in cancer intervention. International Journal of Cancer. ,vol. 62, pp. 345- 350 ,(1995) , 10.1002/IJC.2910620319
Alexander M. Klibanov, Asymmetric transformations catalyzed by enzymes in organic solvents Accounts of Chemical Research. ,vol. 23, pp. 114- 120 ,(1990) , 10.1021/AR00172A004
Shinkichi Tawata, Shigehiko Taira, Naotada Kobamoto, Jun Zhu, Masanobu Ishihara, Seizen Toyama, Synthesis and Antifungal Activity of Cinnamic Acid Esters Bioscience, Biotechnology, and Biochemistry. ,vol. 60, pp. 909- 910 ,(1996) , 10.1271/BBB.60.909
H Stamatis, P Christakopoulos, D Kekos, B.J Macris, F.N Kolisis, Studies on the synthesis of short-chain geranyl esters catalysed by Fusarium oxysporum esterase in organic solvents Journal of Molecular Catalysis B-enzymatic. ,vol. 4, pp. 229- 236 ,(1998) , 10.1016/S1381-1177(98)00003-4
Richard A. Larson, The antioxidants of higher plants Phytochemistry. ,vol. 27, pp. 969- 978 ,(1988) , 10.1016/0031-9422(88)80254-1
Antonio Ballesteros, Uwe Bornscheuer, Andreas Capewell, Didier Combes, Jean-Stéphane Condoret, Kerstin Koenig, Fragiskos N. Kolisis, Alain Marty, Ulrich Menge, Thomas Scheper, Haralambos Stamatis, Aris Xenakis, Enzymes in non-conventional phases Biocatalysis and Biotransformation. ,vol. 13, pp. 1- 42 ,(1995) , 10.3109/10242429509040103