Ultrafast Self-Healing Nanocomposites via Infrared Laser and Their Application in Flexible Electronics

作者: Shuwen Wu , Jinhui Li , Guoping Zhang , Yimin Yao , Gang Li

DOI: 10.1021/ACSAMI.6B15476

关键词:

摘要: The continuous evolution toward flexible electronics with mechanical robust property and restoring structure simultaneously places high demand on a set of polymeric material substrate. Herein, we describe composite composed polyurethane based Diels–Alder chemistry (PU-DA) covalently linked functionalized graphene nanosheets (FGNS), which shows infrared (IR) laser self-healing properties at ambient conditions is therefore suitable for substrate applications. strength can be tuned by varying the amount FGNS breaking reach as 36 MPa only 0.5 wt % loading. On rupture, initial are restored more than 96% healing efficiency after 1 min irradiation time 980 nm IR laser. Especially, this highest value reported in self-healable materials DA systems until now, exhibits volume resistivity up to 5.6...

参考文章(63)
Pengfei Du, Meiyin Wu, Xuanxuan Liu, Zhen Zheng, Xinling Wang, Thomas Joncheray, Yuefan Zhang, Diels-Alder-Based Crosslinked Self-Healing Polyurethane/Urea from Polymeric Methylene Diphenyl Diisocyanate Journal of Applied Polymer Science. ,vol. 131, ,(2014) , 10.1002/APP.40234
Jay R. Lomeda, Condell D. Doyle, Dmitry V. Kosynkin, Wen-Fang Hwang, James M. Tour, Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets Journal of the American Chemical Society. ,vol. 130, pp. 16201- 16206 ,(2008) , 10.1021/JA806499W
Jun Ling, Min Zhi Rong, Ming Qiu Zhang, Photo-stimulated self-healing polyurethane containing dihydroxyl coumarin derivatives Polymer. ,vol. 53, pp. 2691- 2698 ,(2012) , 10.1016/J.POLYMER.2012.04.016
Darren J. Lipomi, Michael Vosgueritchian, Benjamin C-K. Tee, Sondra L. Hellstrom, Jennifer A. Lee, Courtney H. Fox, Zhenan Bao, Skin-like pressure and strain sensors based on transparent elastic films of carbon nanotubes Nature Nanotechnology. ,vol. 6, pp. 788- 792 ,(2011) , 10.1038/NNANO.2011.184
Yuxi Xu, Lu Zhao, Hua Bai, Wenjing Hong, Chun Li, Gaoquan Shi, Chemically converted graphene induced molecular flattening of 5,10,15,20-tetrakis(1-methyl-4-pyridinio)porphyrin and its application for optical detection of cadmium(II) ions. Journal of the American Chemical Society. ,vol. 131, pp. 13490- 13497 ,(2009) , 10.1021/JA905032G
P. Martin, Wound Healing--Aiming for Perfect Skin Regeneration Science. ,vol. 276, pp. 75- 81 ,(1997) , 10.1126/SCIENCE.276.5309.75
Xiaoming Sun, Zhuang Liu, Kevin Welsher, Joshua Tucker Robinson, Andrew Goodwin, Sasa Zaric, Hongjie Dai, None, Nano-Graphene Oxide for Cellular Imaging and Drug Delivery. Nano Research. ,vol. 1, pp. 203- 212 ,(2008) , 10.1007/S12274-008-8021-8
Won Gyu Bae, Doogon Kim, Moon Kyu Kwak, Laura Ha, Seong Min Kang, Kahp Y. Suh, Enhanced Skin Adhesive Patch with Modulus-Tunable Composite Micropillars Advanced Healthcare Materials. ,vol. 2, pp. 109- 113 ,(2013) , 10.1002/ADHM.201200098
Xiangxu Chen, Matheus A Dam, Kanji Ono, Ajit Mal, Hongbin Shen, Steven R Nutt, Kevin Sheran, Fred Wudl, A Thermally Re-mendable Cross-Linked Polymeric Material Science. ,vol. 295, pp. 1698- 1702 ,(2002) , 10.1126/SCIENCE.1065879