Effect of silicate and phosphate additives on the kinetics of the oxygen evolution reaction in valve-regulated lead/acid batteries
作者： M.P. Vinod , K. Vijayamohanan , S.N. Joshi
DOI: 10.1016/S0378-7753(97)02609-8
关键词:
摘要: … This communication reports studies of the effect of sodium silicate and phosphoric acid additives on the kinetics of oxygen evolution on PbO 2 electrodes in sulfuric acid electrolyte. The …
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B. D. McNicol, D. A. J. Rand, Power sources for electric vehicles Elsevier. ,(1984)
M.P. Vinod, K. Vijayamohanan, Effect of gelling on the open circuit potential against time transients of Pb/PbSO4 electrodes at various states of charge Journal of Applied Electrochemistry. ,vol. 24, pp. 44- 51 ,(1994) , 10.1007/BF00243328
H. Dietz, J. Garche, K. Wiesener, The effect of additives on the positive lead—acid battery electrode Journal of Power Sources. ,vol. 14, pp. 305- 319 ,(1985) , 10.1016/0378-7753(85)80046-X
D. Pavlov, Z. Dinev, Mechanism of the Electrochemical Oxidation of Lead to Lead Dioxide Electrode in H 2 SO 4 Solution Journal of The Electrochemical Society. ,vol. 127, pp. 855- 863 ,(1980) , 10.1149/1.2129770
M.P. Vinod, K. Vijayamohanan, Effect of silicate adsorption on the double layer capacitance and exchange current density of the Pb/PbSO4 electrode reaction Journal of Applied Electrochemistry. ,vol. 25, pp. 80- 87 ,(1995) , 10.1007/BF00251269
E. Voss, Effects of phosphoric acid additions on the behaviour of the lead—acid cell: A review Journal of Power Sources. ,vol. 24, pp. 171- 184 ,(1988) , 10.1016/0378-7753(88)80113-7
M.K. Dimitrov, Oxygen evolution on lead dioxide in sulphuric acid solutions Journal of Power Sources. ,vol. 31, pp. 121- 124 ,(1990) , 10.1016/0378-7753(90)80060-Q
D. H. Collins, James A. Plambeck, Power Sources 3 ,(1971)
M.P. Vinod, K. Vijayamohanan, Effect of gelling on the electrode kinetics of the Pb/PbSO4 and hydrogen-electrode reactions in maintenance-free lead/acid batteries Journal of Power Sources. ,vol. 50, pp. 67- 79 ,(1994) , 10.1016/0378-7753(93)01883-J
T. Rogachev, Effect of antimony on the anodic corrosion of lead and oxygen evolution at the Pb/PbO2/H2O/O2/H2SO4 electrode system Journal of Power Sources. ,vol. 23, pp. 331- 340 ,(1988) , 10.1016/0378-7753(88)80077-6