A New Pathway to 2-Arylbenzoxazoles and 2-Arylbenzothiazoles Via One-Pot Oxidative Cyclization Reactions Under Iron-Organic Framework Catalysis
作者： Son H Doan , Chau B Tran , An LN Cao , Nhan TH Le , Nam TS Phan
DOI: 10.1007/S10562-019-02747-1
关键词:
摘要: Iron-organic framework MOF-235 was synthesized, and consequently utilized as a productive heterogeneous catalyst for the synthesis of 2-arylbenzoxazoles 2-arylbenzothiazoles via one-pot oxidative cyclization reactions between 2-aminophenols or 2-aminothiophenols alcohols. The transformation considerably controlled by oxidant nature solvent, system di-tert-butylperoxide with xylene led to best yield major products. presented higher catalytic efficiency than number MOF-based catalysts established homogeneous catalysts. Recovering reutilizing possible while its activity retained. To our knowledge, this iron-catalyzed produce under catalysis conditions not previously reported in literature.
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