Solvent Applications of 2-Methyltetrahydrofuran in Organometallic and Biphasic Reactions
作者： David F. Aycock
DOI: 10.1021/OP060155C
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摘要: … /2 ) of MeTHF place it between THF and Et 2 O in solvent polarity. The donor number (DN) in Table 1 for MeTHF 2 suggests that it is a weaker Lewis base than Et 2 … > MeTHF > Et 2 O as …
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sci-hub.se 参考文章(13)
Richard C. Larock, Reagents for Organic Synthesis ,(1967)
R. B. Bates, L. M. Kroposki, D. E. Potter, Cycloreversions of anions from tetrahydrofurans. Convenient synthesis of lithium enolates of aldehydes Journal of Organic Chemistry. ,vol. 37, pp. 560- 562 ,(1972) , 10.1021/JO00969A007
Veejendra K. Yadav, Alex G. Fallis, Regioselective cleavage of 2-methyltetrahydrofuran: a versatile synthesis of 1-halo-4-pentanols and 4-halo-1-pantanols Journal of Organic Chemistry. ,vol. 51, pp. 3372- 3374 ,(1986) , 10.1021/JO00367A025
Weiling Cai, James L. Colony, Heather Frost, James P. Hudspeth, Peter M. Kendall, Ashwin M. Krishnan, Teresa Makowski, Duane J. Mazur, James Phillips, David H. Brown Ripin, Sally Gut Ruggeri, Jay F. Stearns, Timothy D. White, Investigation of Practical Routes for the Kilogram-Scale Production of cis-3-Methylamino-4-methylpiperidines Organic Process Research & Development. ,vol. 9, pp. 51- 56 ,(2005) , 10.1021/OP049808K
Roderic P. Quirk, Dennis E. Kester, Solvation of alkyllithium compounds. Steric effects on heats of interaction of bases with hexameric versus tetrameric alkyllithiums Journal of Organometallic Chemistry. ,vol. 127, pp. 111- 125 ,(1977) , 10.1016/S0022-328X(00)84201-1
Robert R. Hentz, Stefan J. Rzad, Gas-phase radiolysis of benzene The Journal of Physical Chemistry. ,vol. 72, pp. 1027- 1031 ,(1968) , 10.1021/J100849A042
Gerold U. Bublitz, Steven G. Boxer, Effective Polarity of Frozen Solvent Glasses in the Vicinity of Dipolar Solutes Journal of the American Chemical Society. ,vol. 120, pp. 3988- 3992 ,(1998) , 10.1021/JA971665C
John A. Ragan, David J. am Ende, Steven J. Brenek, Shane A. Eisenbeis, Robert A. Singer, Derek L. Tickner, John J. Teixeira, Brian C. Vanderplas, Neil Weston, Safe Execution of a Large-Scale Ozonolysis: Preparation of the Bisulfite Adduct of 2-Hydroxyindan-2-carboxaldehyde and Its Utility in a Reductive Amination Organic Process Research & Development. ,vol. 7, pp. 155- 160 ,(2003) , 10.1021/OP0202235
J. Ducom, Basicité des solvants des organomagnésiens Journal of Organometallic Chemistry. ,vol. 59, pp. 83- 96 ,(1973) , 10.1016/S0022-328X(00)95022-8
Brett L. Lucht, David B. Collum, ETHEREAL SOLVATION OF LITHIUM HEXAMETHYLDISILAZIDE : UNEXPECTED RELATIONSHIPS OF SOLVATION NUMBER, SOLVATION ENERGY, AND AGGREGATION STATE Journal of the American Chemical Society. ,vol. 117, pp. 9863- 9874 ,(1995) , 10.1021/JA00144A012