High‐field LMR spectra of ClO2 tuned by the avoidance of Zeeman level crossings
作者： Hiromichi Uehara , Kohzo Hakuta
DOI: 10.1063/1.441153
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摘要: Laser magnetic resonance of the ν1 band stable ClO2 radical has exhibited clearly resolved spectra at high fields. Many these were well described by a new‐type Zeeman tuning due to avoidance level crossings between ΔN=±1 levels, induced spin–rotation interaction. An extensive description high‐field was given. From analysis, molecular constants for (100) state 35ClO2 determined as ν1=945.5921(22) cm−1, A=1.7355(4) B=0.3303(8) and C=0.2762(7) cm−1.
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