Avoided crossings in the far-infrared laser magnetic resonance spectrum of HCO
作者： John M Brown , H.E Radford , Trevor J Sears
DOI: 10.1016/0022-2852(91)90031-5
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摘要: Abstract Several transitions in the far-infrared spectrum of HCO radical have been detected by technique laser magnetic resonance (LMR). The spectra assigned to both a- and b-dipole fitted together with previous microwave, millimeter-wave, infrared measurements determine a full set parameters for its ground state. In particular, signals arising from avoided crossing levels 808 716 field analyzed used values off-diagonal components spinrotation, proton dipolar hyperfine, anisotropic g-tensors which are responsible mixing states. reduced spin-rotation parameter ( ϵ ab + ba ) has separated into component parts imposition constraint = A B .
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