A THEORETICAL STUDY OF THE POLAROGRAPHIC REDUCTION OF SULFANILAMIDE DERIVATIVES
作者： S. Quartieri , L. Benedetti , R. Andreoli , A. Rastelli
DOI: 10.1016/S0022-0728(81)80154-4
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摘要: Abstract The polarographic reduction in an aprotic solvent (DMF) of a series 19 sulfanilamide derivatives has been discussed the light CNDO/2 calculations. main results are: (1) relationship between half-wave potential and energy lowest unoccupied molecular orbital (LUMO); (2) evidence C-S-N moiety as electroactive center for electron uptake; (3) preference S-N bond over S-C reductive cleavage.
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