Investigation on the removal of SO3 in ammonia-based WFGD system

作者: Rongting Huang , Ran Yu , Hao Wu , Danping Pan , Yaping Zhang

DOI: 10.1016/J.CEJ.2016.01.020

关键词:

摘要: Abstract The SO3 removal properties were investigated in the wet flue gas desulfurization (WFGD) system. relationship of aerosol emission and concentration was explored experimentally based on ammonia impacts operating parameters, such as liquid-to-gas ratio (L/G), temperature, superficial velocity, particle efficiency studied. results showed that when increased, higher although sizes became smaller within measurement range electrical low pressure impactor (ELPI). When 12 mg/Nm3 47 mg/Nm3, respectively, aerosols emitted from WFGD system similar morphologies. Under same conditions, efficiencies ammonia-based than those limestone–gypsum system, both which rose with increase concentrations. In WFGD, would be improved L/G raised temperature velocity reduced. Two mechanisms proposed processes. One collision trap mechanism other heterogeneous reaction mechanism. sulfuric acid formed though quenching process hot measured to mainly submicron particles. For these particles, Brownian diffusion proved predominant processes, rather inertial impaction.

参考文章(21)
Hiroyuki Kamata, Hiroaki Ohara, Katsumi Takahashi, Akinori Yukimura, Yorimasa Seo, SO2 oxidation over the V2O5/TiO2 SCR catalyst Catalysis Letters. ,vol. 73, pp. 79- 83 ,(2001) , 10.1023/A:1009065030750
Daniel Fleig, Klas Andersson, Filip Johnsson, Influence of Operating Conditions on SO3 Formation during Air and Oxy-Fuel Combustion Industrial & Engineering Chemistry Research. ,vol. 51, pp. 9483- 9491 ,(2012) , 10.1021/IE301303C
Noel De Nevers, Air pollution control engineering ,(1994)
R.K. Srivastava, C.A. Miller, C. Erickson, R. Jambhekar, Emissions of sulfur trioxide from coal-fired power plants. Journal of The Air & Waste Management Association. ,vol. 54, pp. 750- 762 ,(2004) , 10.1080/10473289.2004.10470943
Zhiqiang Wang, Qingchao Huan, Chenlu Qi, Liqiang Zhang, Lin Cui, Xiren Xu, Chunyuan Ma, Study on the Removal of Coal Smoke SO3 with CaO Energy Procedia. ,vol. 14, pp. 1911- 1917 ,(2012) , 10.1016/J.EGYPRO.2011.12.1187
A. P. Colburn, A. G. Edison, Prevention of Fog in Cooler-Condensers Industrial & Engineering Chemistry. ,vol. 33, pp. 457- 458 ,(1941) , 10.1021/IE50376A007
Jiyoung Ahn, Ryan Okerlund, Andrew Fry, Eric G. Eddings, Sulfur trioxide formation during oxy-coal combustion International Journal of Greenhouse Gas Control. ,vol. 5, ,(2011) , 10.1016/J.IJGGC.2011.05.009
L. Brachert, T. Kochenburger, K. Schaber, Facing the Sulfuric Acid Aerosol Problem in Flue Gas Cleaning: Pilot Plant Experiments and Simulation Aerosol Science and Technology. ,vol. 47, pp. 1083- 1091 ,(2013) , 10.1080/02786826.2013.824549
Reinhold Spörl, Lawrence Belo, Kalpit Shah, Rohan Stanger, Roman Giniyatullin, Jörg Maier, Terry Wall, Günter Scheffknecht, Mercury Emissions and Removal by Ash in Coal-Fired Oxy-fuel Combustion Energy & Fuels. ,vol. 28, pp. 5296- 5306 ,(2014) , 10.1021/EF4014604