Lattice parameters and thermal expansion of the T2-phase of the Nb–Si–B system investigated by high-temperature X-ray diffraction

作者: Geovani Rodrigues , Carlos Angelo Nunes , Paulo Atsushi Suzuki , Gilberto Carvalho Coelho

DOI: 10.1016/J.INTERMET.2003.09.015

关键词:

摘要: Abstract The lattice parameters and thermal expansion coefficients ( α a c ) of the T 2 -phase Nb–Si–B system with different boron contents were determined from high temperature X-ray diffraction data (298–1473 K). Alloys nominal compositions Nb 62.5 Si 37.5 , 64 30 B 6 14.4 21.6 (at.%) prepared high-purity materials through arc melting heat-treatment under vacuum. Both decrease increasing content. A significant in is observed content while remains practically unchanged, diminishing anisotropy ratio / approximately 1.2 at binary composition to 0.7 .

参考文章(25)
C.J Rawn, J.H Schneibel, C.M Hoffmann, C.R Hubbard, The crystal structure and thermal expansion of Mo5SiB2 Intermetallics. ,vol. 9, pp. 209- 216 ,(2001) , 10.1016/S0966-9795(00)00113-8
T. Nakashima, Y. Umakoshi, Anisotropy of electrical resistivity and thermal expansion of single-crystal Ti5Si3 Philosophical Magazine Letters. ,vol. 66, pp. 317- 321 ,(1992) , 10.1080/09500839208219052
K Ito, K Ihara, K Tanaka, M Fujikura, M Yamaguchi, Physical and mechanical properties of single crystals of the T2 phase in the Mo–Si–B system Intermetallics. ,vol. 9, pp. 591- 602 ,(2001) , 10.1016/S0966-9795(01)00049-8
R. A. Young, A. Sakthivel, T. S. Moss, C. O. Paiva-Santos, DBWS-9411 – an upgrade of the DBWS*.* programs for Rietveld refinement with PC and mainframe computers Journal of Applied Crystallography. ,vol. 28, pp. 366- 367 ,(1995) , 10.1107/S0021889895002160
M. Göken, R. Sakidja, W.D. Nix, J.H. Perepezko, Microstructural mechanical properties and yield point effects in Mo alloys Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 319, pp. 902- 908 ,(2001) , 10.1016/S0921-5093(01)01086-3
J.H Schneibel, M.J Kramer, D.S Easton, A Mo–Si–B intermetallic alloy with a continuous α-Mo matrix Scripta Materialia. ,vol. 46, pp. 217- 221 ,(2002) , 10.1016/S1359-6462(01)01227-1
M. E. Schlesinger, The Si-Ta (silicon-tantalum) system Journal of Phase Equilibria. ,vol. 15, pp. 90- 95 ,(1994) , 10.1007/BF02667688
K. Yoshimi, S. Nakatani, T. Suda, S. Hanada, H. Habazaki, Oxidation behavior of Mo5SiB2-based alloy at elevated temperatures Intermetallics. ,vol. 10, pp. 407- 414 ,(2002) , 10.1016/S0966-9795(02)00013-4
C.A. Nunes, R. Sakidja, Z. Dong, J.H. Perepezko, Liquidus projection for the Mo-rich portion of the Mo–Si–B ternary system Intermetallics. ,vol. 8, pp. 327- 337 ,(2000) , 10.1016/S0966-9795(99)00088-6
J. J. Williams, M. J. Kramer, M. Akinc, Thermal expansion of Ti5Si3 with Ge, B, C, N, or O additions Journal of Materials Research. ,vol. 15, pp. 1780- 1785 ,(2000) , 10.1557/JMR.2000.0257