A Metal Enhanced Flow-Injection Chemiluminescence Method for the Rapid Determination of Norfloxacin in Pharmaceutical Formulations and Serum Sample
作者： Mohammad Kamruzzaman , Taslima Ferdous , Al-Mahmnur Alam , Sang-Hak Lee , So-Yeun Kim
DOI: 10.5012/BKCS.2011.32.2.639
关键词:
摘要: A simple and highly sensitive chemiluminescence method to determine norfloxacin (NFLX) has been proposed by measuring the (CL) intensities using a flow injection (FI) system. The CL intensity of luminol- system is strongly enhanced addition Cu (II) in alkaline condition. substantially increased after NFLX into luminol--Cu enhancement effect attributed catalytic due interaction with which forms complex catalyst. Under optimal conditions, sensitizing proportional concentration range (r = 0.9994) detection limit () . had good reproducibility relative standard deviation (RSD, n 5) 1.6% for NFLX. possible reaction mechanism also discussed. This successfully applied determination trace amount pharmaceutical preparations serum samples.
koreascience.or.kr参考文章(30)
John M. Beale, John H. Block, Wilson and Gisvold's Textbook of Organic Medicinal and Pharmaceutical Chemistry ,(1991)
Charles Owens Wilson, Ole Gisvold, Textbook of organic medicinal and pharmaceutical chemistry. Lippincott. ,(1954)
Li-Hua Nie, Hui-Chun Zhao, Xu Wang, Lin Yi, Yan Lu, Lin-Pei Jin, Hui-Min Ma, Determination of lomefloxacin by terbium sensitized chemiluminescence method. Analytical and Bioanalytical Chemistry. ,vol. 374, pp. 1187- 1190 ,(2002) , 10.1007/S00216-002-1553-Y
Zhongju Yang, Xiaoli Wang, Weidong Qin, Huichun Zhao, Capillary electrophoresis-chemiluminescence determination of norfloxacin and prulifloxacin. Analytica Chimica Acta. ,vol. 623, pp. 231- 237 ,(2008) , 10.1016/J.ACA.2008.06.023
M. S. Rizk, F. Belal, F. A. Ibrahim, S. M. Ahmed, Z. A. Sheribah, Polarographic Determination of Some 4‐Quinolone Antibacterials via Their Ni(II)‐Complexes Electroanalysis. ,vol. 12, pp. 531- 534 ,(2000) , 10.1002/(SICI)1521-4109(200005)12:7<531::AID-ELAN531>3.0.CO;2-D
Isao Mochida, Kenjiro Takeshita, Transition metal ions on molecular sieves. II. Catalytic activities of transition metal ions on molecular sieves for the decomposition of hydrogen peroxide The Journal of Physical Chemistry. ,vol. 78, pp. 1653- 1657 ,(1974) , 10.1021/J100609A011
Hanwen Sun, Peiyun Chen, Fei Wang, A novel chemiluminescence reaction system for the determination of norfloxacin with Ag(III) complex. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 74, pp. 819- 824 ,(2009) , 10.1016/J.SAA.2009.08.021
Qingfa Tang, Tongtong Yang, Xiaomei Tan, Jiabo Luo, Simultaneous determination of fluoroquinolone antibiotic residues in milk sample by solid-phase extraction-liquid chromatography-tandem mass spectrometry. Journal of Agricultural and Food Chemistry. ,vol. 57, pp. 4535- 4539 ,(2009) , 10.1021/JF900513B
Ching-Ling Cheng, Chia-Hung Fu, Chen-Hsi Chou, Determination of norfloxacin in rat liver perfusate using capillary electrophoresis with laser-induced fluorescence detection Journal of Chromatography B. ,vol. 856, pp. 381- 385 ,(2007) , 10.1016/J.JCHROMB.2007.06.008
Lun Wang, Ping Yang, Yongxin Li, Hongqi Chen, Maoguo Li, Fabao Luo, A flow injection chemiluminescence method for the determination of fluoroquinolone derivative using the reaction of luminol and hydrogen peroxide catalyzed by gold nanoparticles. Talanta. ,vol. 72, pp. 1066- 1072 ,(2007) , 10.1016/J.TALANTA.2006.12.050