Mössbauer Studies of Iodine Bond Hybridization in Iodomethanes
作者： Benjamin S. Ehrlich , Morton Kaplan
DOI: 10.1063/1.1671330
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摘要: The Mossbauer effect of the 57.6 keV transition in 127I has been used to investigate iodine bonding CH3I, CH2I2, CHI3, and CI4 at 4.2°K. data unambiguously imply existence a small amount s hybridization orbitals. This increases approximately linearly through series from ∼0% ∼8% CH3I. ionic character C–I bond also results are compared with several semiempirical predictions based on NQR data. Separate experiments using 27.8‐keV 129I have yielded consistent CH129I3 absorber.
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