Mössbauer Effect in 129I Derivatives of Methane

作者: S. Bukshpan , T. Sonnino

DOI: 10.1063/1.1668011

关键词:

摘要: The Mossbauer effect in the 27.8‐keV transition of 129I was used to investigate electronic structure solid CH3I, CHI3, and CI4. From quadrupole split spectra observed at 85°K isomer shift coupling constants were derived. asymmetry parameter η found be 0. C–I bond derived for three cases.

参考文章(10)
B. P. Dailey, C. H. Townes, The Ionic Character of Diatomic Molecules The Journal of Chemical Physics. ,vol. 23, pp. 118- 123 ,(1955) , 10.1063/1.1740508
Hugh Robinson, H. G. Dehmelt, Walter Gordy, Nuclear Quadrupole Couplings in Solid Bromides and Iodides Journal of Chemical Physics. ,vol. 22, pp. 511- 515 ,(1954) , 10.1063/1.1740097
S. Bukshpan, R. H. Herber, Mössbauer Effect in SnI4 The Journal of Chemical Physics. ,vol. 46, pp. 3375- 3378 ,(1967) , 10.1063/1.1841225
C. H. Townes, B. P. Dailey, Nuclear Quadrupole Effects and Electronic Structure of Molecules in the Solid State The Journal of Chemical Physics. ,vol. 20, pp. 35- 40 ,(1952) , 10.1063/1.1700192
B. P. Dailey, Halogen Bond Character in the Alkyl Halides The Journal of Chemical Physics. ,vol. 33, pp. 1641- 1643 ,(1960) , 10.1063/1.1731476
Y. Reggev, S. Bukshpan, M. Pasternak, D. Segal, A constant acceleration Mössbauer spectrometer utilizing a multichannel analyzer modified for forward-backward address scaling Nuclear Instruments and Methods. ,vol. 52, pp. 193- 196 ,(1967) , 10.1016/0029-554X(67)90220-0
M. Pasternak, T. Sonnino, Studies of IBr, ICl, and I2Cl6 Crystal Properties by Means of the Mössbauer Effect in 129I. I. Chemical Bonds The Journal of Chemical Physics. ,vol. 48, pp. 1997- 2003 ,(1968) , 10.1063/1.1669004
M. Pasternak, A. Simopoulos, Y. Hazony, Mössbauer Effect in Molecular Iodine Crystals Physical Review. ,vol. 140, pp. A1892- A1896 ,(1965) , 10.1103/PHYSREV.140.A1892
Fritz Bischoff, Royce D. Stauffer, The Dispersion of Testosterone in Aqueous Bovine Serum Albumin Solution Journal of the American Chemical Society. ,vol. 76, pp. 1962- 1965 ,(1954) , 10.1021/JA01636A078
Frederick George Mann, Bernard Charles Saunders, Practical Organic Chemistry ,(1965)