Mössbauer Investigation of Frozen Solutions of 129I2
作者： S. Bukshpan , C. Goldstein , T. Sonnino
DOI: 10.1063/1.1670075
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摘要: The Mossbauer effect in the 27.8‐keV level of 129I was used to investigate frozen solutions I2 hexane, CCI4, and benzene at 88°K solid argon 22°K. quadrupole couplings isomer shifts CCl4, (inert solvents) were found be very similar, average values being e2qQ = − 2255 ± 30 Mc/sec (Q of127I) δ(ZnTe source) = + 0.094 ± 0.005 cm/sec. These are interpreted as belonging free iodine molecule. For a coupling e2qQ = − 2412 shift δ = + 0.076 cm/sec obtained. agreement with electron transfer from ring
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sci-hub.se 参考文章(11)
M. Pasternak, T. Sonnino, Studies of IBr, ICl, and I2Cl6 Crystal Properties by Means of the Mössbauer Effect in 129I. II. Lattice Dynamics The Journal of Chemical Physics. ,vol. 48, pp. 2004- 2009 ,(1968) , 10.1063/1.1669005
S. Bukshpan, R. H. Herber, Mössbauer Effect in SnI4 The Journal of Chemical Physics. ,vol. 46, pp. 3375- 3378 ,(1967) , 10.1063/1.1841225
R. Bersohn, Intermolecular Bonding in the Solid Halogens The Journal of Chemical Physics. ,vol. 36, pp. 3445- 3454 ,(1962) , 10.1063/1.1732478
Y. Reggev, S. Bukshpan, M. Pasternak, D. Segal, A constant acceleration Mössbauer spectrometer utilizing a multichannel analyzer modified for forward-backward address scaling Nuclear Instruments and Methods. ,vol. 52, pp. 193- 196 ,(1967) , 10.1016/0029-554X(67)90220-0
S. Bukshpan, T. Sonnino, Mössbauer Effect in 129I Derivatives of Methane Journal of Chemical Physics. ,vol. 48, pp. 4442- 4444 ,(1968) , 10.1063/1.1668011
M. Pasternak, T. Sonnino, Studies of IBr, ICl, and I2Cl6 Crystal Properties by Means of the Mössbauer Effect in 129I. I. Chemical Bonds The Journal of Chemical Physics. ,vol. 48, pp. 1997- 2003 ,(1968) , 10.1063/1.1669004
M. Pasternak, A. Simopoulos, Y. Hazony, Mössbauer Effect in Molecular Iodine Crystals Physical Review. ,vol. 140, pp. A1892- A1896 ,(1965) , 10.1103/PHYSREV.140.A1892
O. Hassel, Structures of electron-transfer and related molecular complexes in the solid state Molecular Physics. ,vol. 1, pp. 241- 246 ,(1958) , 10.1080/00268975800100301
S. Aono, Charge-Transfer Forces in Molecular Compounds. II Benzene-Iodine Complex Progress of Theoretical Physics. ,vol. 22, pp. 313- 320 ,(1959) , 10.1143/PTP.22.313
Robert S. Mulliken, Molecular Compounds and their Spectra. II Journal of the American Chemical Society. ,vol. 74, pp. 811- 824 ,(1952) , 10.1021/JA01123A067