Analysis and Modeling of the Hydroisomerization Process for n-Hexane
作者： E. V. Pisarenko , A. B. Ponomarev , V. N. Pisarenko
DOI: 10.1134/S004057951801013X
关键词:
摘要: A stage six-path mechanism for the reaction of n-hexane hydroisomerization on a BEA Pt-zeolite catalyst has been proposed. The mass flow rate in feed stream varies range 0.7−2.8 h−1; mole ratio hydrogen to 2.7–14.6; reactor temperature falls from 453 573 K; and gas pressure 1.0–10.0 atm. Thirty experiments have carried out. In product stream, concentrations n-hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, 2,3-dimethylbutane, propane, C1-alkanes, C2-alkanes are analyzed by chromatography. kinetic model constructed hydroisomerization, which contains 15 constants. Based results laboratory experiments, constants estimated method nonlinear least squares. shown correspond with experiment selected field experimentation.
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sci-hub.se 参考文章(11)
M. Guisnet, V. Fouche, M. Belloum, J.P. Bournonville, C. Travers, Isomerization of n-hexane on platinum dealuminated mordenite catalysts II. Kinetic study Applied Catalysis. ,vol. 71, pp. 295- 306 ,(1991) , 10.1016/0166-9834(91)85087-C
José Luis García-Gutiérrez, José Luis Cano, Laura Olivia Alemán-Vázquez, Federico Jiménez-Cruz, Study of selectivity of MoO3-catalyzed C6–C7 hydrocarbons hydroisomerization: Mechanistic insights into the formation of carbonaceous deposits on the catalyst surface Fuel. ,vol. 94, pp. 532- 543 ,(2012) , 10.1016/J.FUEL.2011.11.032
N. N. Ziyatdinov, Computer simulation and optimization in chemical technology Theoretical Foundations of Chemical Engineering. ,vol. 48, pp. 539- 540 ,(2014) , 10.1134/S0040579514050261
Patrícia M. Lima, Teresita Garetto, Célio L. Cavalcante, Dilson Cardoso, Isomerization of n-hexane on Pt-Ni catalysts supported on nanocrystalline H-BEA zeolite Catalysis Today. ,vol. 172, pp. 195- 202 ,(2011) , 10.1016/J.CATTOD.2011.02.031
E. V. Pisarenko, V. N. Pisarenko, Kinetics of the reaction of olefin synthesis from methanol and dimethyl ether Theoretical Foundations of Chemical Engineering. ,vol. 42, pp. 822- 831 ,(2008) , 10.1134/S0040579508060043
L. Belandria, N. Marín-Astorga, E. García, E. Sosa, F. Aguirre, M. Villarroel, A. Uzcátegui, F. Imbert, Catalytic activity of Pt and Pd catalysts supported on HWP/HMS in the selective hydroisomerization of n-pentane. Effect of reaction temperature Catalysis Today. ,vol. 172, pp. 2- 7 ,(2011) , 10.1016/J.CATTOD.2011.04.050
A. S. Kinyakin, E. A. Glushachenkova, P. N. Borutskii, A. S. Shuvalov, Yu. A. Pisarenko, Kinetics of the low-temperature isomerization of n-hexane on the NIP-3A catalyst in an isothermal flow reactor Theoretical Foundations of Chemical Engineering. ,vol. 42, pp. 815- 821 ,(2008) , 10.1134/S0040579508060031
Hsu Chiang, Aditya Bhan, Catalytic consequences of hydroxyl group location on the kinetics of n-hexane hydroisomerization over acidic zeolites Journal of Catalysis. ,vol. 283, pp. 98- 107 ,(2011) , 10.1016/J.JCAT.2011.07.006
E. V. Pisarenko, V. N. Pisarenko, Analysis and simulation of the nonlinear kinetics of reacting chemical systems Theoretical Foundations of Chemical Engineering. ,vol. 47, pp. 128- 135 ,(2013) , 10.1134/S004057951302005X
Miguel A. Baltanas, Kristiaan K. Van Raemdonck, Gilbert F. Froment, Sergio R. Mohedas, Fundamental kinetic modeling of hydroisomerization and hydrocracking on noble metal-loaded faujasites. 1. Rate parameters for hydroisomerization Industrial & Engineering Chemistry Research. ,vol. 28, pp. 899- 910 ,(1989) , 10.1021/IE00091A004