New hybrid ditopic ligands containing fused phenanthroline and crown ether units

作者: Craig R. Rice , Ana Guerrero , Zöe R. Bell , Rowena L. Paul , Graham R. Motson

DOI: 10.1039/B008378J

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摘要: Reaction of 5,6-dihydroxy-1,10-phenanthroline with various poly(ethylene)glycol-ditosylates affords, in good yield, a series ligands which phenanthroline binding site is attached to an adjacent crown ether unit; the NN chelating may be coordinated {Ru(bipy)2}2+ units afford [Ru(bipy)3]2+ derivatives pendant units, can bind alkali metal ions.

参考文章(7)
Michael P. Murchie, John W. Bovenkamp, André Rodrigue, Kimberley A. Watson, Suzanne Fortier, Complexes of 15-crown-5 and cyclohexano-15-crown-5 with lithium, sodium, and potassium phenoxide having macrocycle: salt ratios of 1:1 and 1:2. The crystal structures of two polymorphs of 15-crown-5•2LiOPh Canadian Journal of Chemistry. ,vol. 66, pp. 2515- 2523 ,(1988) , 10.1139/V88-395
Scott Chadwick, Ulrich Englich, Karin Ruhlandt-Senge, Lewis Base Coordination versus Cation−π Interaction in Monomeric and Hexameric Potassium Thiolates Organometallics. ,vol. 16, pp. 5792- 5803 ,(1997) , 10.1021/OM9707230
Witold Paw, Richard Eisenberg, Synthesis, Characterization, and Spectroscopy of Dipyridocatecholate Complexes of Platinum. Inorganic Chemistry. ,vol. 36, pp. 2287- 2293 ,(1997) , 10.1021/IC9610851
Vivian Wing-Wah Yam, Vicky Wing-Man Lee, Fu Ke, Kam-Wing Michael Siu, Synthesis, Photophysics, and Electrochemistry of Ruthenium(II) Polypyridine Complexes with Crown Ether Pendants Inorganic Chemistry. ,vol. 36, pp. 2124- 2129 ,(1997) , 10.1021/IC961400J
Roman Boulatov, Bin Du, Edward A. Meyers, Sheldon G. Shore, Two Novel Lithium−15-Crown-5 Complexes: An Extended LiCl Chain Stabilized by Crown Ether and a Dimeric Complex Stabilized by Hydrogen Bonding with Water Inorganic Chemistry. ,vol. 38, pp. 4554- 4558 ,(1999) , 10.1021/IC9904790
Kimberly A. Watson, Suzanne Fortier, Michael P. Murchie, John W. Bovenkamp, Crown ether complexes exhibiting unusual 1:2 macrocycle salt ratios: X-ray crystal structures of cyclohexano-15-crown-5•2LiOPh, cyclohexano-15-crown-5•2NaOPh, and 15-crown-5•2NaOPh Canadian Journal of Chemistry. ,vol. 69, pp. 687- 695 ,(1991) , 10.1139/V91-103