Chirality-Driven Parallel and Antiparallel β-Sheet Secondary Structures of Phe-Ala Lipodipeptides.
作者： Shuwei Lin , Jiaming Qin , Yi Li , Baozong Li , Yonggang Yang
DOI: 10.1021/ACS.LANGMUIR.7B01942
关键词:
摘要: Four Phe–Ala lipodipeptides with different stereochemical structures are observed to self-assemble into twisted nanoribbons in water. The handedness of the is controlled by chirality phenylalanine near alkyl chain, while stacking phenyl and carbonyl groups determined alanine at C-terminal. homochiral heterochiral parallel antiparallel β-sheet structures, respectively. 1H NMR, FTIR, X-ray diffraction, circular dichroism characterizations indicate that these phenomena mainly driven interaction between neighboring H-bonding among amide groups.
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Abhishek Baral, Shibaji Basak, Kingshuk Basu, Ashkan Dehsorkhi, Ian W. Hamley, Arindam Banerjee, Time-dependent gel to gel transformation of a peptide based supramolecular gelator. Soft Matter. ,vol. 11, pp. 4944- 4951 ,(2015) , 10.1039/C5SM00808E
Yi Li, Sibing Wang, Min Xiao, Mingliang Wang, Zhibin Huang, Baozong Li, Yonggang Yang, Chirality of the 1,4-phenylene-silica nanoribbons at the nano and angstrom levels. Nanotechnology. ,vol. 24, pp. 035603- 035603 ,(2013) , 10.1088/0957-4484/24/3/035603
Masahiro Suzuki, Mariko Yumoto, Mutsumi Kimura, Hirofusa Shirai, Kenji Hanabusa, New Low-Molecular-Mass Gelators Based onL-Lysine: Amphiphilic Gelators and Water-Soluble Organogelators Helvetica Chimica Acta. ,vol. 87, pp. 1- 10 ,(2004) , 10.1002/HLCA.200490025
Wenqing Peng, Masao Motonaga, Julian R. Koe, Chirality Control in Optically Active Polysilane Aggregates Journal of the American Chemical Society. ,vol. 126, pp. 13822- 13826 ,(2004) , 10.1021/JA046235I
Mark M. Green, Michael P. Reidy, Robert D. Johnson, Graham Darling, Daniel J. O'Leary, Grant Willson, Macromolecular Stereochemistry: The Out-of-Proportion Influence of Optically Active Comonomers on the Conformational Characteristics of Polyisocyanates. The Sergeants and Soldiers Experiment Journal of the American Chemical Society. ,vol. 111, pp. 6452- 6454 ,(1989) , 10.1021/JA00198A084
Masahiro Suzuki, Teruaki Sato, Hirofusa Shirai, Kenji Hanabusa, Powerful low-molecular-weight gelators based on L-valine and L-isoleucine with various terminal groups New Journal of Chemistry. ,vol. 30, pp. 1184- 1191 ,(2006) , 10.1039/B604847A
Honggang Cui, Takahiro Muraoka, Andrew G. Cheetham, Samuel I. Stupp, Self-assembly of giant peptide nanobelts. Nano Letters. ,vol. 9, pp. 945- 951 ,(2009) , 10.1021/NL802813F
Yanyan Xie, Xiangchao Wang, Renliang Huang, Wei Qi, Yuefei Wang, Rongxin Su, Zhimin He, Electrostatic and Aromatic Interaction-Directed Supramolecular Self-Assembly of a Designed Fmoc-Tripeptide into Helical Nanoribbons Langmuir. ,vol. 31, pp. 2885- 2894 ,(2015) , 10.1021/LA504757C
Mischa Zelzer, Rein V. Ulijn, Next-generation peptide nanomaterials: molecular networks, interfaces and supramolecular functionality. Chemical Society Reviews. ,vol. 39, pp. 3351- 3357 ,(2010) , 10.1039/C0CS00035C
Liam C. Palmer, Samuel I. Stupp, Molecular Self-Assembly into One-Dimensional Nanostructures Accounts of Chemical Research. ,vol. 41, pp. 1674- 1684 ,(2008) , 10.1021/AR8000926