Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids.
作者： Takahiro Nishimura , Sho Hirabayashi , Yuichi Yasuhara , Tamio Hayashi
DOI: 10.1021/JA058763F
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摘要: Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids proceeded in high yields regio- and enantioselectivity to give chiral allylphosphine oxides up 98% ee. The structural determination the key intermediate, a π-allylrhodium complex, was successful establish catalytic cycle reaction.
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