Enhancement of hydrogen reaction in a micro-channel by catalyst segmentation

作者: G CHEN , Y CHAO , C CHEN

DOI: 10.1016/J.IJHYDENE.2008.02.071

关键词:

摘要: Abstract The paper addresses the combustion characteristics of multi-segment catalysts in a micro-reactor by numerical simulation with detailed heterogeneous and homogeneous chemistries. effect catalyst is delineated terms different dispositions, flow conditions reactor properties. With fixed total length (1 cm), reveals better performance than single catalyst. space between segments reduces inhibition reactions promotes this region since neighboring help to maintain high wall temperature. Therefore, can shift upstream results dispositions show that more has but distance no obvious effects due fast reaction rate hydrogen. For conditions, indicate disposition conversion ratio even though there fluid for fuel-lean condition. inlet velocities benefit on lower velocity. However, it extend blowout Finally dimension material are simulated. Although strengthen small channel, still benefit. thermal conductivity do not have difference These be used design catalytic hydrogen/air reactions.

参考文章(24)
R.J. Kee, F.M. Rupley, E. Meeks, J.A. Miller, CHEMKIN-III: A FORTRAN chemical kinetics package for the analysis of gas-phase chemical and plasma kinetics Other Information: PBD: May 1996. ,(1996) , 10.2172/481621
Kaoru Maruta, Koichi Takeda, Jeongmin Ahn, Kevin Borer, Lars Sitzki, Paul D. Ronney, Olaf Deutschmann, Extinction limits of catalytic combustion in microchannels 29th International Symposium on Combustion. ,vol. 29, pp. 957- 963 ,(2002) , 10.1016/S1540-7489(02)80121-3
N.S. Kaisare, D.G. Vlachos, Optimal reactor dimensions for homogeneous combustion in small channels Catalysis Today. ,vol. 120, pp. 96- 106 ,(2007) , 10.1016/J.CATTOD.2006.07.036
O. Deutschmann, R. Schmidt, F. Behrendt, J. Warnat, NUMERICAL MODELING OF CATALYTIC IGNITION Symposium (International) on Combustion. ,vol. 26, pp. 1747- 1754 ,(1996) , 10.1016/S0082-0784(96)80400-0
Guan-Bang Chen, Chih-Peng Chen, Chih-Yung Wu, Yei-Chin Chao, Effects of catalytic walls on hydrogen/air combustion inside a micro-tube Applied Catalysis A-general. ,vol. 332, pp. 89- 97 ,(2007) , 10.1016/J.APCATA.2007.08.011
D.G. Norton, D.G. Vlachos, Combustion characteristics and flame stability at the microscale: a CFD study of premixed methane/air mixtures Chemical Engineering Science. ,vol. 58, pp. 4871- 4882 ,(2003) , 10.1016/J.CES.2002.12.005
Symeon Karagiannidis, John Mantzaras, Gregory Jackson, Konstantinos Boulouchos, Hetero-/homogeneous combustion and stability maps in methane-fueled catalytic microreactors Proceedings of the Combustion Institute. ,vol. 31, pp. 3309- 3317 ,(2007) , 10.1016/J.PROCI.2006.07.121
Trinh K. Pham, Derek Dunn-Rankin, William A. Sirignano, Miniature-scale liquid-fuel-film combustor Proceedings of the Combustion Institute. ,vol. 29, pp. 925- 931 ,(2002) , 10.1016/S1540-7489(02)80117-1
George A. Boyarko, Chih-Jen Sung, Steven J. Schneider, Catalyzed combustion of hydrogen–oxygen in platinum tubes for micro-propulsion applications Proceedings of the Combustion Institute. ,vol. 30, pp. 2481- 2488 ,(2005) , 10.1016/J.PROCI.2004.08.203