The vibrational properties of gold(III) chloride complexes of bipyridyl and 1,10-phenanthroline

作者: A.A. McConnell , D.H. Brown , W.E. Smith

DOI: 10.1016/0584-8539(82)80206-7

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摘要: Abstract Raman and i.r. spectra of complexes gold(III) with chloride bipyridyl or 1,10-phenanthroline ligands are reported. The in both the aromatic-ring stretching region metal—halide assigned. compounds four-coordinate. It is concluded that nitrogen bridge two AuCl 3 moieties (L 2 )Au Cl 6 a polymer containing planar units bridged by ions.

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