How to accurately determine the uptake of hydrogen in carbonaceous materials

作者: C ZHANG

DOI: 10.1016/J.IJHYDENE.2003.12.001

关键词:

摘要: A volumetric apparatus for adsorption measurement of hydrogen in carbonaceous materials aimed at storage was constructed. The performance the assessed by helium and one kind vapor-grown graphitic nanofiber (GNF). bulk gas amounts determined equations state Modified-Benedic-Webb-Rubin (MBWR), ideal Soave-Redlich-Kwong (SRK) under conditions present study are compared. Two different methods processing experimental data to determine residual volume studied. Experimental results theoretic analysis showed that method described this paper could accurately Gibbs excess amount materials. Although GNF used did not show a significant capacity hydrogen, obtained would provide favorable reference development material storage.

参考文章(10)
Tetsu Kiyobayashi, Hiroyuki T Takeshita, Hideaki Tanaka, Nobuhiko Takeichi, Andreas Züttel, Louis Schlapbach, Nobuhiro Kuriyama, Hydrogen adsorption in carbonaceous materials–: How to determine the storage capacity accurately Journal of Alloys and Compounds. ,vol. 330, pp. 666- 669 ,(2002) , 10.1016/S0925-8388(01)01436-0
J.U. Keller, F. Dreisbach, H. Rave, R. Staudt, M. Tomalla, Measurement of Gas Mixture Adsorption Equilibria of Natural Gas Compounds on Microporous Sorbents Adsorption-journal of The International Adsorption Society. ,vol. 5, pp. 199- 214 ,(1999) , 10.1023/A:1008998117996
F.Lamari Darkrim, P. Malbrunot, G.P. Tartaglia, Review of hydrogen storage by adsorption in carbon nanotubes International Journal of Hydrogen Energy. ,vol. 27, pp. 193- 202 ,(2002) , 10.1016/S0360-3199(01)00103-3
S HYNEK, Hydrogen storage by carbon sorption International Journal of Hydrogen Energy. ,vol. 22, pp. 601- 610 ,(1997) , 10.1016/S0360-3199(96)00185-1
Hongwei Zhu, Chunhua Li, Xuesong Li, Cailu Xu, Zongqiang Mao, Ji Liang, Dehai Wu, Hydrogen storage by platelet-carbon fibers at room temperature Materials Letters. ,vol. 57, pp. 32- 35 ,(2002) , 10.1016/S0167-577X(02)00694-8
A.C. Dillon, K.M. Jones, T.A. Bekkedahl, C.H. Kiang, D.S. Bethune, Heben, M.J, Storage of hydrogen in single-walled carbon nanotubes Nature. ,vol. 386, pp. 377- 379 ,(1997) , 10.1038/386377A0
W.Z Huang, X.B Zhang, J.P Tu, F.Z Kong, J.X Ma, F Liu, H.M Lu, C.P Chen, The effect of pretreatments on hydrogen adsorption of multi-walled carbon nanotubes Materials Chemistry and Physics. ,vol. 78, pp. 144- 148 ,(2003) , 10.1016/S0254-0584(02)00305-X
Li Zhou, Yaping Zhou, Determination of compressibility factor and fugacity coefficient of hydrogen in studies of adsorptive storage International Journal of Hydrogen Energy. ,vol. 26, pp. 597- 601 ,(2001) , 10.1016/S0360-3199(00)00123-3
J. Karl Johnson, John A. Zollweg, Keith E. Gubbins, The Lennard-Jones equation of state revisited Molecular Physics. ,vol. 78, pp. 591- 618 ,(1993) , 10.1080/00268979300100411
C Park, CD Tan, R Hidalgo, R TK Baker, NM Rodriguez, Hydrogen Storage in Graphite Nanofibers Journal of Physical Chemistry B. ,vol. 102, pp. 4253- 4256 ,(1998) , 10.1021/JP980114L