Effect of epoxidation level on thermal properties and ionic conductivity of epoxidized natural rubber solid polymer nanocomposite electrolytes
作者： Fatin Harun , Chin Han Chan , Lai Har Sim , Tan Winie , Nurul Fatahah Asyqin Zainal
DOI: 10.1063/1.4928850
关键词:
摘要: Effect of epoxide content on the thermal and conductivity properties epoxidized natural rubber (ENR) solid polymer nanocomposite electrolytes was investigated. Commercial available having 25 (ENR25) 50 mole% (ENR50) epoxide, respectively were incorporated with lithium perchlorate (LiClO4) salt titanium dioxide (TiO2) nanofiller via solution casting method. The characterized by differential scanning calorimetry (DSC) impedance spectroscopy (IS) for their conductivity, respectively. It evident that introduction LiClO4 causes a greater increase in glass transition temperature (Tg) ionic ENR50 as compared to ENR25. Upon addition TiO2 ENR/LiClO4 system, remarkable Tg elevation observed both ENRs where reveals more pronounced changes. is interesting note they exhibit different phenomenon loading ENR25 sho...
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