Synthesis and structure of neutral ?-arene complex (?6-C6H5Me)U(AlCl4)3
作者： A. V. Garbar , M. R. Leonov , L. N. Zakharov , Yu. T. Struchkov
DOI: 10.1007/BF01433993
关键词:
摘要: A new neutral π-arene complex of trivalent uranium, (η6-C6H5Me)U(AlCl4)3 (1), was obtained by the reductive Freidel-Crafts reaction. The crystal structure 1 determined single X-ray diffraction analysis. U atom in is bound to C6H5Me group η6 mechanism and linked three AICl4 groups through two g-CI bridges. coordination a distorted pentagonal bipyramid which center arene ring one apical position, bridging Cl atoms occupy other vertices.
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