The facile approach to fabricate gold nanoparticles and their application on the hydration and dehydrogenation reactions

作者: Ronghui Huang , Yong Fu , Wei Zeng , Liang Zhang , Dawei Wang

DOI: 10.1016/J.JORGANCHEM.2017.09.016

关键词:

摘要: Abstract A mild and practical strategy to prepare gold nanoparticles was developed. This particles supported mesoporous silica fabricated from AuPPh 3 Cl under conditions characterized through transmission electron microscopy, energy dispersive X-ray, X-ray power diffraction photoelectron spectrometry. Interestingly, it observed that this nanoparticle effective the hydration of alkynes dehydrogenation alcohols. The catalytic system can tolerate a variety functional groups afford corresponding products in good excellent yields.

参考文章(67)
Sadegh Rostamnia, Turaj Rahmani, Hongchuan Xin, Pd(PrSO3)2@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C–X activations in air and water Journal of Industrial and Engineering Chemistry. ,vol. 32, pp. 218- 224 ,(2015) , 10.1016/J.JIEC.2015.08.019
Ashish Kumar, Vanama Pavan Kumar, Amirineni Srikanth, Venkataraman Vishwanathan, Komandur VR Chary, None, Vapor Phase Oxidation of Benzyl Alcohol over Nano Au/SBA-15 Catalysts: Effect of Preparation Methods Catalysis Letters. ,vol. 146, pp. 35- 46 ,(2016) , 10.1007/S10562-015-1656-7
Lindelani Q. Qwabe, Venkata D.B.C. Dasireddy, Sooboo Singh, Holger B. Friedrich, Preferential CO oxidation in a hydrogen-rich stream over gold supported on Ni–Fe mixed metal oxides for fuel cell applications International Journal of Hydrogen Energy. ,vol. 41, pp. 2144- 2153 ,(2016) , 10.1016/J.IJHYDENE.2015.12.060
A. Beloqui Redondo, M. Ranocchiari, J. A. van Bokhoven, Synthesis of sub-nanometer gold particles on modified silica. Dalton Transactions. ,vol. 45, pp. 2983- 2988 ,(2016) , 10.1039/C5DT04957A
Adriana Zaleska-Medynska, Martyna Marchelek, Magdalena Diak, Ewelina Grabowska, Noble metal-based bimetallic nanoparticles: the effect of the structure on the optical, catalytic and photocatalytic properties. Advances in Colloid and Interface Science. ,vol. 229, pp. 80- 107 ,(2016) , 10.1016/J.CIS.2015.12.008
Chun-Hsia Liu, Chih-Yu Lin, Jeng-Lung Chen, Nien-Chu Lai, Chia-Min Yang, Jin-Ming Chen, Kueih-Tzu Lu, Metal oxide-containing SBA-15-supported gold catalysts for base-free aerobic homocoupling of phenylboronic acid in water Journal of Catalysis. ,vol. 336, pp. 49- 57 ,(2016) , 10.1016/J.JCAT.2016.01.004
Shalini Nekkanti, Karuna Veeramani, Niggula Praveen Kumar, Nagula Shankaraiah, Microwave-assisted direct oxidative synthesis of α-ketoamides from aryl methyl ketones and amines by a water soluble Cu(I)-complex Green Chemistry. ,vol. 18, pp. 3439- 3447 ,(2016) , 10.1039/C6GC00557H
Jinsuo Gao, Xueying Zhang, Yan Yang, Jun Ke, Xinyong Li, Yaobin Zhang, Feng Tan, Jingwen Chen, Xie Quan, Surface-passivated SBA-15-supported gold nanoparticles: Highly improved catalytic activity and selectivity toward hydrophobic substrates Chemistry-an Asian Journal. ,vol. 8, pp. 934- 938 ,(2013) , 10.1002/ASIA.201300088
Xu Li, Stella See Soon Fang, Jaclyn Teo, Yong Lim Foo, Armando Borgna, Ming Lin, Ziyi Zhong, Activation and Deactivation of Au–Cu/SBA-15 Catalyst for Preferential Oxidation of CO in H2-Rich Gas ACS Catalysis. ,vol. 2, pp. 360- 369 ,(2012) , 10.1021/CS200536A