[3,3]-Sigmatropic rearrangements of fluorocarbanions
作者： V.G. Andreev , A.F. Kolomiets , A.V. Fokin
DOI: 10.1016/S0022-1139(00)81173-2
关键词:
摘要: Abstract The reactions of terminal polyfluoroalkenes with 2,3-unsaturated alcohols and deprotonation the addition products these reagents under mild conditions give unsaturated fluoroaliphatic acids their derivatives. cause unusually formation compounds is spontaneous [3,3]-sigmatropic rearrangement initially formed fluorocarbanions associated elimination fluoride ion. probability realizing sigmatropic shifts determined by structural peculiarities intermediates generated.
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