Pd-catalyzed synthesis of allylic silanes from allylic ethers.

作者: Ralph Moser , Takashi Nishikata , Bruce H. Lipshutz

DOI: 10.1021/OL9023908

关键词:

摘要: Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water the only medium using micellar catalysis.

参考文章(42)
Keiya Mizutani, Hideki Yorimitsu, Koichiro Oshima, Cobalt- and rhodium-catalyzed cross-coupling reaction of allylic ethers and halides with organometallic reagents Tetrahedron. ,vol. 62, pp. 1410- 1415 ,(2006) , 10.1016/J.TET.2005.11.032
Michinori Suginome, Yoshihiko Ito, Regio- and stereoselective synthesis of boryl-substituted allylsilanes via transition metal-catalyzed silaboration Journal of Organometallic Chemistry. ,vol. 680, pp. 43- 50 ,(2003) , 10.1016/S0022-328X(03)00441-8
Ryo Shintani, Yoshitaka Ichikawa, Tamio Hayashi, Jinshui Chen, Yoshiaki Nakao, Tamejiro Hiyama, Catalytic Asymmetric Synthesis of Allylsilanes through Rhodium/Chiral Diene-Catalyzed 1,4-Addition of Alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes Organic Letters. ,vol. 9, pp. 4643- 4645 ,(2007) , 10.1021/OL702125Q
Laurent Chabaud, Philippe James, Yannick Landais, Allylsilanes in Organic Synthesis − Recent Developments European Journal of Organic Chemistry. ,vol. 2004, pp. 3173- 3199 ,(2004) , 10.1002/EJOC.200300789
Mamoru Tobisu, Yusuke Kita, Yusuke Ano, Naoto Chatani, Rhodium-catalyzed silylation and intramolecular arylation of nitriles via the silicon-assisted cleavage of carbon-cyano bonds. Journal of the American Chemical Society. ,vol. 130, pp. 15982- 15989 ,(2008) , 10.1021/JA804992N
Hiroshi Onoue, Ichiro Moritani, Shun-Ichi Murahashi, Reaction of cycloalkanone enamines with allylic compounds in the presence of palladium complexes Tetrahedron Letters. ,vol. 14, pp. 121- 124 ,(1973) , 10.1016/S0040-4039(01)95593-5