Visible-Light-Driven Rotation of Molecular Motors in a Dual-Function Metal–Organic Framework Enabled by Energy Transfer
作者： Wojciech Danowski , Fabio Castiglioni , Andy S. Sardjan , Simon Krause , Lukas Pfeifer
DOI: 10.1021/JACS.0C03063
关键词:
摘要: The visible-light-driven rotation of an overcrowded alkene-based molecular motor strut in a dual-function metal-organic framework (MOF) is reported. Two types functional linkers, palladium-porphyrin photosensitizer and bispyridine-derived motor, were used to construct the capable harvesting low-energy green light power rotary motion. was introduced using postsynthetic solvent-assisted linker exchange (SALE) method, structure material confirmed by powder (PXRD) single-crystal X-ray (SC-XRD) diffraction. large decrease phosphorescence lifetime intensity porphyrin MOFs upon introduction pillars confirms efficient triplet-to-triplet energy transfer between linkers motor. Near-infrared Raman spectroscopy revealed that visible light-driven proceeds solid state at rates similar those observed solution.
acs.org
narcis.nl参考文章(73)
Vincenzo Balzani, Alberto Credi, Margeritha Venturi, Molecular Devices and Machines– A Journey into the Nano World Wiley-VCH Verlag GmbH & Co. KGaA. ,(2003) , 10.1002/3527601600
Nagatoshi Koumura, Robert W. J. Zijlstra, Richard A. van Delden, Nobuyuki Harada, Ben L. Feringa, Light-driven monodirectional molecular rotor Nature. ,vol. 401, pp. 152- 155 ,(1999) , 10.1038/43646
Kelong Zhu, Christopher A. O'Keefe, V. Nicholas Vukotic, Robert W. Schurko, Stephen J. Loeb, A molecular shuttle that operates inside a metal–organic framework Nature Chemistry. ,vol. 7, pp. 514- 519 ,(2015) , 10.1038/NCHEM.2258
Hailian Li, Mohamed Eddaoudi, M. O'Keeffe, O. M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework Nature. ,vol. 402, pp. 276- 279 ,(1999) , 10.1038/46248
Caleb A. Kent, Brian P. Mehl, Liqing Ma, John M. Papanikolas, Thomas J. Meyer, Wenbin Lin, Energy transfer dynamics in metal-organic frameworks Journal of the American Chemical Society. ,vol. 132, pp. 12767- 12769 ,(2010) , 10.1021/JA102804S
Omar K. Farha, Christos D. Malliakas, Mercouri G. Kanatzidis, Joseph T. Hupp, Control over Catenation in Metal−Organic Frameworks via Rational Design of the Organic Building Block Journal of the American Chemical Society. ,vol. 132, pp. 950- 952 ,(2010) , 10.1021/JA909519E
Maria-Melanie Russew, Stefan Hecht, Photoswitches: From Molecules to Materials Advanced Materials. ,vol. 22, pp. 3348- 3360 ,(2010) , 10.1002/ADMA.200904102
V. Nicholas Vukotic, Kristopher J. Harris, Kelong Zhu, Robert W. Schurko, Stephen J. Loeb, Metal-organic frameworks with dynamic interlocked components. Nature Chemistry. ,vol. 4, pp. 456- 460 ,(2012) , 10.1038/NCHEM.1354
Wesley R. Browne, Ben L. Feringa, Making molecular machines work Nature Nanotechnology. ,vol. 1, pp. 25- 35 ,(2006) , 10.1038/NNANO.2006.45
Vivian Wing-Wah Yam, Chi-Chiu Ko, Nianyong Zhu, Photochromic and luminescence switching properties of a versatile diarylethene-containing 1,10-phenanthroline ligand and its rhenium(I) complex. Journal of the American Chemical Society. ,vol. 126, pp. 12734- 12735 ,(2004) , 10.1021/JA047446Q