Double-resonance spectroscopy of radicals: higher electronic excited states of 1- and 2-naphthylmethyl, 1-phenylpropargyl and 9-anthracenylmethyl
作者： Gerard D. O’Connor , Gabrielle V.G. Woodhouse , Tyler P. Troy , Timothy W. Schmidt
DOI: 10.1080/00268976.2015.1012127
关键词:
摘要: Multiple pulsed-laser frequencies are used to extract the excitation spectra of Dn ← D0 transitions (n > 1) 1- and 2-naphthylmethyl, 1-phenylpropargyl 9-anthracenylmethyl radicals. Bands are, respectively, observed at 27993, 27478, 32437 25063 cm−1, with respective widths (at half maximum) 292, 290, 149 326 cm−1. On basis comparison ab initio vertical energies, for radical assigned as D3 D0. The transition 1-naphthylmethyl is ambiguously either or both D4 From wide Lorentzian profiles observed, lifetimes a few tens fs inferred, spectral precluding this class molecule from being responsible long-unidentified diffuse interstellar bands.
harvard.edu
sci-hub.se 参考文章(63)
L. D'hendecourt, A. Leger, Are polycyclic aromatic hydrocarbons the carriers of the diffuse interstellar bands in the visible Astronomy and Astrophysics. ,vol. 146, pp. 81- 85 ,(1985)
G. P. van der Zwet, L. J. Allamandola, Polycyclic aromatic hydrocarbons and the diffuse interstellar bands Astronomy and Astrophysics. ,vol. 146, pp. 76- 80 ,(1985) , 10.1007/978-94-009-4672-9_51
E.B. Jochnowitz, J.P. Maier, Electronic spectroscopy of carbon chains Molecular Physics. ,vol. 106, pp. 2093- 2106 ,(2008) , 10.1080/00268970802208588
Alexander A. Granovsky, Extended multi-configuration quasi-degenerate perturbation theory: the new approach to multi-state multi-reference perturbation theory. Journal of Chemical Physics. ,vol. 134, pp. 214113- 214113 ,(2011) , 10.1063/1.3596699
Neil J. Reilly, Masakazu Nakajima, Tyler P. Troy, Nahid Chalyavi, Kieran A. Duncan, Klaas Nauta, Scott H. Kable, Timothy W. Schmidt, Spectroscopic Identification of the Resonance-Stabilizedcis- andtrans-1-Vinylpropargyl Radicals Journal of the American Chemical Society. ,vol. 131, pp. 13423- 13429 ,(2009) , 10.1021/JA904521C
H. Ding, T. W. Schmidt, T. Pino, A. E. Boguslavskiy, F. Güthe, J. P. Maier, Gas phase electronic spectra of the linear carbon chains HC2n+1H (n=3–6,9) Journal of Chemical Physics. ,vol. 119, pp. 814- 819 ,(2003) , 10.1063/1.1578476
Masaru Fukushima, Kinichi Obi, Jet spectroscopy of benzyl and benzyl‐α‐d2 Journal of Chemical Physics. ,vol. 96, pp. 4224- 4232 ,(1992) , 10.1063/1.462815
Gerard D. O’Connor, George B. Bacskay, Gabrielle V. G. Woodhouse, Tyler P. Troy, Klaas Nauta, Timothy W. Schmidt, Excitation spectra of large jet-cooled polycyclic aromatic hydrocarbon radicals: 9-anthracenylmethyl (C15H11) and 1-pyrenylmethyl (C17H11). Journal of Physical Chemistry A. ,vol. 117, pp. 13899- 13907 ,(2013) , 10.1021/JP4088833
Thomas D. Varberg, Klaas Nauta, Tyler P. Troy, Timothy W. Schmidt, Timothy W. Schmidt, Nigel T. Lucas, Masakazu Nakajima, Gregory F. Metha, Damian L. Kokkin, The Optical Spectrum of a Large Isolated Polycyclic Aromatic Hydrocarbon: Hexa-peri-hexabenzocoronene, C42H18 The Astrophysical Journal. ,vol. 681, ,(2008) , 10.1086/590207
Tyler P. Troy, Masakazu Nakajima, Nahid Chalyavi, Raphaël G. C. R. Clady, Klaas Nauta, Scott H. Kable, Timothy W. Schmidt, Identification of the jet-cooled 1-indanyl radical by electronic spectroscopy Journal of Physical Chemistry A. ,vol. 113, pp. 10279- 10283 ,(2009) , 10.1021/JP905831M